Complete 1H and 13C NMR assignments of clerodane diterpenoids of Salvia splendens

Copyright (c) 2006 John Wiley & Sons, Ltd.

Bibliographische Detailangaben
Veröffentlicht in:Magnetic resonance in chemistry : MRC. - 1985. - 44(2006), 10 vom: 01. Okt., Seite 962-5
1. Verfasser: Fontana, Gianfranco (VerfasserIn)
Weitere Verfasser: Savona, Giuseppe, Rodríguez, Benjamín
Format: Aufsatz
Sprache:English
Veröffentlicht: 2006
Zugriff auf das übergeordnete Werk:Magnetic resonance in chemistry : MRC
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Carbon Isotopes Diterpenes, Clerodane Hydrogen 7YNJ3PO35Z
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245 1 0 |a Complete 1H and 13C NMR assignments of clerodane diterpenoids of Salvia splendens 
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520 |a Unambiguous and complete assignments of 1H and 13C NMR chemical shifts for five clerodane diterpenes, four of them isolated from Salvia splendens (salviarin, splendidin and splenolides A and B) and one obtained by acetylation of splenolide A, are presented. The assignments are based on 2D shift-correlated [1H,1H-COSY, 1H,13C-gHSQC-1J(C,H) and 1H,13C-gHMBC-nJ(C,H) (n=2 and 3)] and nuclear Overhauser effect (NOE) experiments. The conformation of the rings of these compounds is supported by the 3J(H,H) values and NOE results 
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