Highly efficient capture and long-term encapsulation of dye by catanionic surfactant vesicles

Vesicles formed from the cationic surfactant, cetyltrimethylammonium tosylate (CTAT) and the anionic surfactant, sodium dodecylbenzenesulfonate (SDBS), were used to sequester the anionic dye carboxyfluorescein. Carboxyfluorescein was efficiently sequestered in CTAT-rich vesicles via two mechanisms:...

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Détails bibliographiques
Publié dans:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 22(2006), 15 vom: 18. Juli, Seite 6461-4
Auteur principal: Wang, Xiang (Auteur)
Autres auteurs: Danoff, Emily J, Sinkov, Nikolai A, Lee, Jae-Ho, Raghavan, Srinivasa R, English, Douglas S
Format: Article
Langue:English
Publié: 2006
Accès à la collection:Langmuir : the ACS journal of surfaces and colloids
Sujets:Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S. Benzenesulfonates Cations Cetrimonium Compounds Fluoresceins Surface-Active Agents trimethylcetylammonium p-toluenesulfonate 1P489GK6AR plus... 6-carboxyfluorescein 3301-79-9 dodecylbenzenesulfonic acid 60NSK897G9
Description
Résumé:Vesicles formed from the cationic surfactant, cetyltrimethylammonium tosylate (CTAT) and the anionic surfactant, sodium dodecylbenzenesulfonate (SDBS), were used to sequester the anionic dye carboxyfluorescein. Carboxyfluorescein was efficiently sequestered in CTAT-rich vesicles via two mechanisms: encapsulation in the inner water pool and electrostatic adsorption to the charged bilayer. The apparent encapsulation efficiency (22%) includes both encapsulated and adsorbed fractions. Entrapment of carboxyfluorescein by SDBS-rich vesicles was not observed. Results show the permeability of the catanionic membrane is an order of magnitude lower than that of phosphatidylcholine vesicles and the loading capacity is more than 10 times greater
Description:Date Completed 16.08.2007
Date Revised 15.11.2012
published: Print
Citation Status MEDLINE
ISSN:1520-5827