Influence of microemulsions on enantioselective synthesis of (R)-cyclopent-2-enol catalyzed by vitamin B12
The influence of microemulsions on the vitamin B12-catalyzed enantioselective isomerization of 1,2-epoxycyclopentane (1) to form (R)-cyclopent-2-enol (2) has been examined. The reaction was initiated by a reduction of vitamin B12 to the Co(I) form by Zn/NH4Cl. The largest enantiomeric excess (e.e.)...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 22(2006), 12 vom: 06. Juni, Seite 5289-93 |
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| Format: | Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2006
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Research Support, U.S. Gov't, Non-P.H.S. Cyclopentanes Emulsions Pentanols Vitamin B 12 P6YC3EG204 |