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DE-627 |
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20231223094038.0 |
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231223s2006 xx ||||| 00| ||eng c |
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|a (NLM)16649776
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|a DE-627
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|e rakwb
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| 041 |
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|a eng
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| 100 |
1 |
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|a Yoshimura, Tomokazu
|e verfasserin
|4 aut
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| 245 |
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|a Equilibrium and dynamic surface tension properties of partially fluorinated quaternary ammonium salt gemini surfactants
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| 264 |
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|c 2006
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| 336 |
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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| 338 |
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|a Band
|b nc
|2 rdacarrier
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|a Date Completed 03.08.2007
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|a Date Revised 02.05.2006
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a The equilibrium and dynamic surface tension properties of a partially fluorinated quaternary ammonium salt gemini surfactant 1,2-bis[dimethyl-(3-perfluoroalkyl-2-hydroxypropyl)ammonium]ethane bromide (C(n)(F)C3-2-C3C(n)F, where n represents fluorocarbon chain lengths of 4, 6, and 8) were investigated, and the effects of the fluorocarbon chain length and the number of chains on them were discussed. The plot of the logarithm of the critical micelle concentration (cmc) against the fluorocarbon chain length for C(n)(F)C3-2-C3C(n)F showed a linear decrease with an increase in chain length. On the basis of the slope of this plot, it was found that the variation in cmc with respect to the chain length is large for fluorinated gemini surfactants. The surface tension at the cmc decreased significantly; this surface tension value is lower than that of conventional fluorinated monomeric surfactants. In particular, the lowest value was 13.7 mN m(-1) for n = 8. Furthermore, it was confirmed that the kinetics of adsorption at the interface decrease with an increase in the fluorocarbon chain length and the concentration
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|a Journal Article
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1 |
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|a Ohno, Akiko
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Esumi, Kunio
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 22(2006), 10 vom: 09. Mai, Seite 4643-8
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:22
|g year:2006
|g number:10
|g day:09
|g month:05
|g pages:4643-8
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|a AR
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| 952 |
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|d 22
|j 2006
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|h 4643-8
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