Density Functional Study of Mo-Carbonyl-Catalyzed Alkynol Cycloisomerization : Comparison with W-Catalyzed Reaction
Mo-catalyzed endo-cycloisomerizations of alkynes tethered to alcohols have been studied using density functional theory, and comparisons were made with the W-catalyzed reaction. The cycloisomerization is initiated with the formation of metal alkyne pi complex and is followed by the rate-determining...
| Publié dans: | Organometallics. - 1998. - 24(2005), 12 vom: 06. Juni, Seite 2921-2929 |
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| Auteur principal: | |
| Autres auteurs: | , , |
| Format: | Article |
| Langue: | English |
| Publié: |
2005
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| Accès à la collection: | Organometallics |
| Sujets: | Journal Article |