Density Functional Study of Mo-Carbonyl-Catalyzed Alkynol Cycloisomerization : Comparison with W-Catalyzed Reaction

Mo-catalyzed endo-cycloisomerizations of alkynes tethered to alcohols have been studied using density functional theory, and comparisons were made with the W-catalyzed reaction. The cycloisomerization is initiated with the formation of metal alkyne pi complex and is followed by the rate-determining...

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Veröffentlicht in:Organometallics. - 1998. - 24(2005), 12 vom: 06. Juni, Seite 2921-2929
1. Verfasser: Nowroozi-Isfahani, Taraneh (VerfasserIn)
Weitere Verfasser: Musaev, Djamaladdin G, McDonald, Frank E, Morokuma, Keiji
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Organometallics
Schlagworte:Journal Article