Mechanistic studies on the conversion of dicobalt octacarbonyl into colloidal cobalt nanoparticles
In situ ATR-FTIR monitoring has allowed the direct study of the effect of additives (trioctylphosphine oxide [TOPO] and oleic acid) on the kinetics and rate of the thermal decomposition of dicobalt octacarbonyl leading to the formation of colloidal cobalt nanoparticles (CoCNPs). The study has shown...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1985. - 22(2006), 8 vom: 11. Apr., Seite 3823-9 |
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| Weitere Verfasser: | , , , |
| Format: | Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2006
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | In situ ATR-FTIR monitoring has allowed the direct study of the effect of additives (trioctylphosphine oxide [TOPO] and oleic acid) on the kinetics and rate of the thermal decomposition of dicobalt octacarbonyl leading to the formation of colloidal cobalt nanoparticles (CoCNPs). The study has shown that additives usually considered as simple surfactants influence the rate and kinetics of the decomposition of dicobalt octacarbonyl. Several of the initial intermediates connecting Co2(CO)8 with CoCNPs have been identified, and a tentative mechanism for the formation of the colloidal nanoparticles has been proposed |
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| Beschreibung: | Date Completed 09.07.2007 Date Revised 04.04.2006 published: Print Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |