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|e rakwb
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| 041 |
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|a eng
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| 100 |
1 |
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|a Pesika, Noshir S
|e verfasserin
|4 aut
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| 245 |
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|a Kinetics of desorption of alkanethiolates on gold
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| 264 |
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|c 2006
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| 336 |
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|b nc
|2 rdacarrier
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|a Date Completed 09.07.2007
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|a Date Revised 04.04.2006
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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| 520 |
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|a Self-assembled monolayers (SAMs) of alkanethiols can undergo reductive desorption and oxidative re-adsorption. The Coulombic efficiency of the oxidative re-adsorption reaction is dependent on the chain length and solution pH. We show that the loss of alkanethiols from the surface after reductive desorption can be explained by a simple model that takes into account diffusion of the thiolate into the bulk solution at a rate that is determined by the bulk solubility. These results provide a quantitative basis for the determination of the loss of alkanethiols from the surface after reductive desorption
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|a Journal Article
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|a Stebe, Kathleen J
|e verfasserin
|4 aut
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| 700 |
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|a Searson, Peter C
|e verfasserin
|4 aut
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| 773 |
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8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 22(2006), 8 vom: 11. Apr., Seite 3474-6
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
1 |
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|g volume:22
|g year:2006
|g number:8
|g day:11
|g month:04
|g pages:3474-6
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