SEBS aggregate patterning at a surface studied by atomic force microscopy

The morphologies of films spin coated from dilute block copolymer solution onto a mica substrate were studied by atomic force microscopy (AFM). Variables of interest were the polymer concentration, solvent, heating temperature, aging, and ultrasonic effect. It is shown that the solution concentratio...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 22(2006), 7 vom: 28. März, Seite 3428-33
1. Verfasser: Han, Xia (VerfasserIn)
Weitere Verfasser: Hu, Jun, Liu, Honglai, Hu, Ying
Format: Aufsatz
Sprache:English
Veröffentlicht: 2006
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Aluminum Silicates Polyethylenes Polymers Polystyrenes Spin Labels styrene-ethylene-butylene-styrene-block copolymer 104521-01-9 mica V8A1AW0880
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520 |a The morphologies of films spin coated from dilute block copolymer solution onto a mica substrate were studied by atomic force microscopy (AFM). Variables of interest were the polymer concentration, solvent, heating temperature, aging, and ultrasonic effect. It is shown that the solution concentration is the predominant factor in determining the shape of the aggregates displayed from spheres and rods to irregular patches with increasing concentration. The solubility parameter of the solvent plays an important role in modifying the distribution and the size of clusters at the surface. The structures of the aggregates at the surface are metastable, which could evolve with temperature from rodlike aggregates into regular stripes when annealed at a temperature higher than the order-disorder transition temperature of SEBS, whereas those in solution could evolve with aging and ultrasonic treatment into a more stable network structure 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
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650 7 |a Polyethylenes  |2 NLM 
650 7 |a Polymers  |2 NLM 
650 7 |a Polystyrenes  |2 NLM 
650 7 |a Spin Labels  |2 NLM 
650 7 |a styrene-ethylene-butylene-styrene-block copolymer  |2 NLM 
650 7 |a 104521-01-9  |2 NLM 
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650 7 |a V8A1AW0880  |2 NLM 
700 1 |a Hu, Jun  |e verfasserin  |4 aut 
700 1 |a Liu, Honglai  |e verfasserin  |4 aut 
700 1 |a Hu, Ying  |e verfasserin  |4 aut 
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