Tetradecylferrocene : ordered molecular array of an organometallic amphiphile in the crystal and in a two-dimensional assembled structure on a surface

Tetradecylferrocene (4, Fc-(CH2)13CH3) was synthesized via lithiation of ferrocene by treatment with tert-butyl lithium, followed by alkylation with 1-bromotetradecane. Complex 4 forms a physisorbed ordered molecular monolayer on the surface of highly oriented pyrolytic graphite (HOPG) that was anal...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 22(2006), 7 vom: 28. März, Seite 3161-5
1. Verfasser: Wedeking, Katrin (VerfasserIn)
Weitere Verfasser: Mu, Zhongcheng, Kehr, Gerald, Fröhlich, Roland, Erker, Gerhard, Chi, Lifeng, Fuchs, Harald
Format: Aufsatz
Sprache:English
Veröffentlicht: 2006
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Tetradecylferrocene (4, Fc-(CH2)13CH3) was synthesized via lithiation of ferrocene by treatment with tert-butyl lithium, followed by alkylation with 1-bromotetradecane. Complex 4 forms a physisorbed ordered molecular monolayer on the surface of highly oriented pyrolytic graphite (HOPG) that was analyzed by scanning tunneling microscopy (STM). It features a lamellar structure with single rows of ferrocenyl moieties separating connecting areas formed by the long alkyl chains which are arranged parallel to each other. The ordering principle of 4 on the surface can be related to the arrangement of Fc-(CH2)13CH3 molecules in the three-dimensional crystal lattice 
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700 1 |a Mu, Zhongcheng  |e verfasserin  |4 aut 
700 1 |a Kehr, Gerald  |e verfasserin  |4 aut 
700 1 |a Fröhlich, Roland  |e verfasserin  |4 aut 
700 1 |a Erker, Gerhard  |e verfasserin  |4 aut 
700 1 |a Chi, Lifeng  |e verfasserin  |4 aut 
700 1 |a Fuchs, Harald  |e verfasserin  |4 aut 
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