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231223s2006 xx ||||| 00| ||eng c |
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|a DE-627
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|e rakwb
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|a eng
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| 100 |
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|a Thünemann, Andreas F
|e verfasserin
|4 aut
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| 245 |
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|a Two-compartment micellar assemblies obtained via aqueous self-organization of synthetic polymer building blocks
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| 264 |
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|c 2006
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|a Band
|b nc
|2 rdacarrier
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|a Date Completed 26.02.2007
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|a Date Revised 07.03.2006
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a We synthesized a symmetric linear ABCBA pentablock copolymer consisting of poly(ethylene oxide), poly(gamma-benzyl l-glutamate), and a poly(perfluoro ether) (fluorolink). The different blocks are highly immiscible with each other and form two-compartment micelles of mainly cylindrical shape in aqueous solution with lengths in the range of 100 to 200 nm and diameters of about 24 nm. The poly(perfluoro ether) (C blocks) forms the liquidlike center of the micelles (d = 6 nm). This is surrounded by a first shell of ca. 2 nm thickness consisting of beta-sheets of poly(gamma-benzyl l-glutamate) (B blocks) and a second 7 nm shell of poly(ethylene oxide) (A blocks). The A blocks provide water solubility, and the B and C blocks form separated hydrophobic compartments. This work is a contribution to the development of multicompartment micelles devoted to mimic transport proteins such as serum albumins in long-term development
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|a Journal Article
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|a Kubowicz, Stephan
|e verfasserin
|4 aut
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|a von Berlepsch, Hans
|e verfasserin
|4 aut
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| 700 |
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|a Möhwald, Helmuth
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 22(2006), 6 vom: 14. März, Seite 2506-10
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:22
|g year:2006
|g number:6
|g day:14
|g month:03
|g pages:2506-10
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|d 22
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