Synthetic and Mechanistic Studies of Strained Heterocycle Opening Reactions Mediated by Zirconium(IV) Imido Complexes

The reactions of the bis(cyclopentadienyl)(tert-butylimido)zirconium complex (Cp(2)Zr=N-t-Bu)(THF) (1) with epoxides, aziridines, and episulfides were investigated. Heterocycles without accessible beta-hydrogens undergo insertion/protonation of the C-X bond to produce 1,2-amino alcohols (X = O) and...

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Publié dans:	Organometallics. - 1998. - 24(2005), 7 vom: 28. März, Seite 1647-1659
Auteur principal:	Blum, Suzanne A (Auteur)
Autres auteurs:	Rivera, Vicki A, Ruck, Rebecca T, Michael, Forrest E, Bergman, Robert G
Format:	Article
Langue:	English
Publié:	2005
Accès à la collection:	Organometallics
Sujets:	Journal Article