Synthesis of quantum dot-tagged submicrometer polystyrene particles by miniemulsion polymerization

Submicrometer fluorescent polystyrene (PS) particles have been synthesized via miniemulsion polymerization using CdSe/ZnS core-shell quantum dots (QDs). The influence of QD concentration, QD coating (either trioctylphosphine oxide (TOPO)-coated or vinyl-functionalized), and surfactant concentration...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 22(2006), 4 vom: 14. Feb., Seite 1810-6
1. Verfasser: Joumaa, Nancy (VerfasserIn)
Weitere Verfasser: Lansalot, Muriel, Théretz, Alain, Elaissari, Abdelhamid, Sukhanova, Alyona, Artemyev, Mikhail, Nabiev, Igor, Cohen, Jacques H M
Format: Aufsatz
Sprache:English
Veröffentlicht: 2006
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Comparative Study Journal Article Research Support, Non-U.S. Gov't Cadmium Compounds Emulsions Polystyrenes Selenium Compounds Sulfides Zinc Compounds cadmium selenide mehr... A7F646JC5C zinc sulfide KPS085631O
LEADER 01000naa a22002652 4500
001 NLM160546915
003 DE-627
005 20231223090322.0
007 tu
008 231223s2006 xx ||||| 00| ||eng c
028 5 2 |a pubmed24n0535.xml 
035 |a (DE-627)NLM160546915 
035 |a (NLM)16460111 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Joumaa, Nancy  |e verfasserin  |4 aut 
245 1 0 |a Synthesis of quantum dot-tagged submicrometer polystyrene particles by miniemulsion polymerization 
264 1 |c 2006 
336 |a Text  |b txt  |2 rdacontent 
337 |a ohne Hilfsmittel zu benutzen  |b n  |2 rdamedia 
338 |a Band  |b nc  |2 rdacarrier 
500 |a Date Completed 09.05.2007 
500 |a Date Revised 15.11.2012 
500 |a published: Print 
500 |a Citation Status MEDLINE 
520 |a Submicrometer fluorescent polystyrene (PS) particles have been synthesized via miniemulsion polymerization using CdSe/ZnS core-shell quantum dots (QDs). The influence of QD concentration, QD coating (either trioctylphosphine oxide (TOPO)-coated or vinyl-functionalized), and surfactant concentration on the polymerization kinetics and the photoluminescence properties of the prepared particles has been analyzed. Polymerization kinetics were not altered by the presence of QDs, whatever their surface coating. Latexes exhibited particle sizes ranging from 100 to 350 nm, depending on surfactant concentration, and a narrow particle size distribution was obtained in all cases. The fluorescence signal of the particles increased with the number of incorporated TOPO-coated QDs. The slight red shift of the emission maximum was correlated with phase separation between PS and QDs, which occurred during the polymerization, locating the QDs in the vicinity of the particle/water interface. QD-tagged particles displayed higher fluorescence intensity with TOPO-coated QDs compared to those with the vinyl moiety. The obtained fluorescent particles open up new opportunities for a variety of applications in biotechnology 
650 4 |a Comparative Study 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 7 |a Cadmium Compounds  |2 NLM 
650 7 |a Emulsions  |2 NLM 
650 7 |a Polystyrenes  |2 NLM 
650 7 |a Selenium Compounds  |2 NLM 
650 7 |a Sulfides  |2 NLM 
650 7 |a Zinc Compounds  |2 NLM 
650 7 |a cadmium selenide  |2 NLM 
650 7 |a A7F646JC5C  |2 NLM 
650 7 |a zinc sulfide  |2 NLM 
650 7 |a KPS085631O  |2 NLM 
700 1 |a Lansalot, Muriel  |e verfasserin  |4 aut 
700 1 |a Théretz, Alain  |e verfasserin  |4 aut 
700 1 |a Elaissari, Abdelhamid  |e verfasserin  |4 aut 
700 1 |a Sukhanova, Alyona  |e verfasserin  |4 aut 
700 1 |a Artemyev, Mikhail  |e verfasserin  |4 aut 
700 1 |a Nabiev, Igor  |e verfasserin  |4 aut 
700 1 |a Cohen, Jacques H M  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1992  |g 22(2006), 4 vom: 14. Feb., Seite 1810-6  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnns 
773 1 8 |g volume:22  |g year:2006  |g number:4  |g day:14  |g month:02  |g pages:1810-6 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 22  |j 2006  |e 4  |b 14  |c 02  |h 1810-6