Adhesion of single polyelectrolyte molecules on silica, mica, and bitumen surfaces

In a recent study (Energy Fuels 2005, 19, 936), a partially hydrolyzed polyacrylamide (HPAM) was used as a process aid to recover bitumen from oil sand ores. It was found that HPAM addition at the bitumen extraction step not only improved bitumen recovery but also enhanced fine solids settling in th...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 22(2006), 4 vom: 14. Feb., Seite 1652-9
1. Verfasser: Long, Jun (VerfasserIn)
Weitere Verfasser: Xu, Zhenghe, Masliyah, Jacob H
Format: Aufsatz
Sprache:English
Veröffentlicht: 2006
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Acrylic Resins Aluminum Silicates Hydrocarbons Petroleum Silicon Dioxide 7631-86-9 asphalt 8052-42-4 mehr... polyacrylamide 9003-05-8 Clay T1FAD4SS2M mica V8A1AW0880
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520 |a In a recent study (Energy Fuels 2005, 19, 936), a partially hydrolyzed polyacrylamide (HPAM) was used as a process aid to recover bitumen from oil sand ores. It was found that HPAM addition at the bitumen extraction step not only improved bitumen recovery but also enhanced fine solids settling in the tailings stream. To understand the role of HPAM, single-molecule force spectroscopy was employed for the first time to measure the desorption/adhesion forces of single HPAM molecules on silica, mica, and bitumen surfaces using an atomic force microscope (AFM). Silicon wafers with an oxidized surface layer and newly cleaved mica were used, respectively, to represent sand grains and clays in oil sands. The force measurements were carried out in deionized water and in commercial plant process water under equilibrium conditions. The desorption/adhesion forces of HPAM obtained on mica, silica, and bitumen surfaces were approximately 200, 40, and 80 pN in deionized water and approximately 100, 50, and 40 pN in the plant process water, respectively. The measured adhesion forces together with the zeta potential values of these surfaces indicate that the polymer would preferentially adsorb onto clay surfaces rather than onto bitumen surfaces. It is the selective adsorption of HPAM that benefits both bitumen recovery and tailings settling when the polymer was added directly to the bitumen extraction process at an appropriate dosage 
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650 7 |a asphalt  |2 NLM 
650 7 |a 8052-42-4  |2 NLM 
650 7 |a polyacrylamide  |2 NLM 
650 7 |a 9003-05-8  |2 NLM 
650 7 |a Clay  |2 NLM 
650 7 |a T1FAD4SS2M  |2 NLM 
650 7 |a mica  |2 NLM 
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700 1 |a Xu, Zhenghe  |e verfasserin  |4 aut 
700 1 |a Masliyah, Jacob H  |e verfasserin  |4 aut 
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