Light-harvesting energy transfer and subsequent electron transfer of cationic porphyrin complexes on clay surfaces

A novel energy-transfer system involving nonaggregated cationic porphyrins adsorbed on an anionic-type clay surface and the electron-transfer reaction that occurs after light harvesting are described. In the clay-porphyrin complexes, photochemical energy transfer from excited singlet zinc porphyrins...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 22(2006), 4 vom: 14. Feb., Seite 1406-8
1. Verfasser: Takagi, Shinsuke (VerfasserIn)
Weitere Verfasser: Eguchi, Miharu, Tryk, Donald A, Inoue, Haruo
Format: Aufsatz
Sprache:English
Veröffentlicht: 2006
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Aluminum Silicates Hydroquinones Porphyrins Zinc J41CSQ7QDS Clay T1FAD4SS2M hydroquinone XV74C1N1AE
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245 1 0 |a Light-harvesting energy transfer and subsequent electron transfer of cationic porphyrin complexes on clay surfaces 
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520 |a A novel energy-transfer system involving nonaggregated cationic porphyrins adsorbed on an anionic-type clay surface and the electron-transfer reaction that occurs after light harvesting are described. In the clay-porphyrin complexes, photochemical energy transfer from excited singlet zinc porphyrins to free-base porphyrins proceeds. The photochemical electron-transfer reaction from an electron donor in solution (hydroquinone) to the adsorbed porphyrin in the excited singlet state was also examined. Because the electron-transfer rate from the hydroquinone to the excited singlet free-base porphyrin is larger than that to the excited singlet zinc porphyrin, we conclude that the energy transfer accelerates the overall electron-transfer reaction 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 7 |a Aluminum Silicates  |2 NLM 
650 7 |a Hydroquinones  |2 NLM 
650 7 |a Porphyrins  |2 NLM 
650 7 |a Zinc  |2 NLM 
650 7 |a J41CSQ7QDS  |2 NLM 
650 7 |a Clay  |2 NLM 
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650 7 |a hydroquinone  |2 NLM 
650 7 |a XV74C1N1AE  |2 NLM 
700 1 |a Eguchi, Miharu  |e verfasserin  |4 aut 
700 1 |a Tryk, Donald A  |e verfasserin  |4 aut 
700 1 |a Inoue, Haruo  |e verfasserin  |4 aut 
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