Characterization of supported solid thin films of Laponite clay. Intercalation of rhodamine 6G laser dye

The morphology of thin films of Laponite (Lap) clay elaborated by the evaporation method and spin-coating technique was analyzed by atomic force microscopy and scanning electron microscopy, indicating a better quality film for the latter procedure. Rhodamine 6G (R6G) laser dye was intercalated into...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 20(2004), 14 vom: 06. Juli, Seite 5709-17
1. Verfasser: Martínez Martínez, V (VerfasserIn)
Weitere Verfasser: López Arbeloa, F, Bañuelos Prieto, J, Arbeloa López, T, López Arbeloa, I
Format: Aufsatz
Sprache:English
Veröffentlicht: 2004
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Aluminum Silicates Coloring Agents Membranes, Artificial Rhodamines Solutions rhodamine 6G 037VRW83CF Clay T1FAD4SS2M
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100 1 |a Martínez Martínez, V  |e verfasserin  |4 aut 
245 1 0 |a Characterization of supported solid thin films of Laponite clay. Intercalation of rhodamine 6G laser dye 
264 1 |c 2004 
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337 |a ohne Hilfsmittel zu benutzen  |b n  |2 rdamedia 
338 |a Band  |b nc  |2 rdacarrier 
500 |a Date Completed 20.03.2007 
500 |a Date Revised 26.10.2019 
500 |a published: Print 
500 |a Citation Status MEDLINE 
520 |a The morphology of thin films of Laponite (Lap) clay elaborated by the evaporation method and spin-coating technique was analyzed by atomic force microscopy and scanning electron microscopy, indicating a better quality film for the latter procedure. Rhodamine 6G (R6G) laser dye was intercalated into these films by ion exchange mechanism, performed by immersing the clay film into adequate dye solutions in which the effect of the dye concentration, immersion time, and nature of the solvent on the adsorption process were checked. The adsorption of R6G at the interlayer space of Lap was analyzed by the X-ray diffraction technique, and the presence of several R6G species (monomers and aggregates) was characterized by absorption and fluorescence spectroscopies. Less viscous solvents lead to higher dye loadings, suggesting a diffusional process for the intercalation of the dye in the interlayer spaces of Lap, and polar solvents favor the swellability of the interlayer space giving rise to a more homogeneous distribution of R6G molecules through the film and decreasing the dye aggregation. With the aging of the samples, the dye molecules can migrate through the interlayer spaces, leading to a more expanded distribution of R6G molecules and to the dye deaggregation 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 7 |a Aluminum Silicates  |2 NLM 
650 7 |a Coloring Agents  |2 NLM 
650 7 |a Membranes, Artificial  |2 NLM 
650 7 |a Rhodamines  |2 NLM 
650 7 |a Solutions  |2 NLM 
650 7 |a rhodamine 6G  |2 NLM 
650 7 |a 037VRW83CF  |2 NLM 
650 7 |a Clay  |2 NLM 
650 7 |a T1FAD4SS2M  |2 NLM 
700 1 |a López Arbeloa, F  |e verfasserin  |4 aut 
700 1 |a Bañuelos Prieto, J  |e verfasserin  |4 aut 
700 1 |a Arbeloa López, T  |e verfasserin  |4 aut 
700 1 |a López Arbeloa, I  |e verfasserin  |4 aut 
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