Effect of hydrophobically modified polymer on salt-induced structural transition in microemulsions

The phase boundaries of the middle-phase microemulsion for NaCl/SDS/H2O/1-heptane/1-pentanol systems in the absence of polymer and in the presence of unmodified poly(acrylamide) (PAM) and hydrophobically modified poly(acrylamide) (HMPAM) have been determined at varying salt concentrations. These thr...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 20(2004), 14 vom: 06. Juli, Seite 5679-82
1. Verfasser: Ma, Xiaojing (VerfasserIn)
Weitere Verfasser: Wang, Xiaoyong, Wang, Jinben, Guo, Donghong, Wang, Yilin, Ye, Jianping, Wang, Zhengping, Yan, Haike
Format: Aufsatz
Sprache:English
Veröffentlicht: 2004
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Emulsions Heptanes Pentanols Polymers Water 059QF0KO0R Acrylamide 20R035KLCI mehr... Sodium Dodecyl Sulfate 368GB5141J Sodium Chloride 451W47IQ8X n-heptane 456148SDMJ n-pentanol M9L931X26Y
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100 1 |a Ma, Xiaojing  |e verfasserin  |4 aut 
245 1 0 |a Effect of hydrophobically modified polymer on salt-induced structural transition in microemulsions 
264 1 |c 2004 
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520 |a The phase boundaries of the middle-phase microemulsion for NaCl/SDS/H2O/1-heptane/1-pentanol systems in the absence of polymer and in the presence of unmodified poly(acrylamide) (PAM) and hydrophobically modified poly(acrylamide) (HMPAM) have been determined at varying salt concentrations. These three middle-phase microemulsions (with HMPAM, with PAM, and without polymer) were studied using interfacial tension measurement, steady-state fluorescence, and time-resolved fluorescence quenching. Compared to the polymer-free system and the system with PAM, the addition of HMPAM significantly enlarges the range of the salt concentrations for the formation of the middle-phase microemulison and causes both the excess oil and aqueous phases to increase in volume at the expense of the middle-phase microemulsion. For the middle-phase microemulsion with HMPAM, the interfacial tensions of the microemulsion phase with the excess oil phase and with the excess aqueous phase are all ultralow and exhibit higher values than those with PAM and without polymer. At the same salt concentration, the apparent surfactant aggregation number in the middle-phase microemulsion with HMPAM has the smallest value among these three systems. All results indicate that the strong interaction of surfactant with hydrophobically modified polymer has a large effect on the formation and properties of the middle-phase microemulsion 
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650 7 |a Pentanols  |2 NLM 
650 7 |a Polymers  |2 NLM 
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650 7 |a 059QF0KO0R  |2 NLM 
650 7 |a Acrylamide  |2 NLM 
650 7 |a 20R035KLCI  |2 NLM 
650 7 |a Sodium Dodecyl Sulfate  |2 NLM 
650 7 |a 368GB5141J  |2 NLM 
650 7 |a Sodium Chloride  |2 NLM 
650 7 |a 451W47IQ8X  |2 NLM 
650 7 |a n-heptane  |2 NLM 
650 7 |a 456148SDMJ  |2 NLM 
650 7 |a n-pentanol  |2 NLM 
650 7 |a M9L931X26Y  |2 NLM 
700 1 |a Wang, Xiaoyong  |e verfasserin  |4 aut 
700 1 |a Wang, Jinben  |e verfasserin  |4 aut 
700 1 |a Guo, Donghong  |e verfasserin  |4 aut 
700 1 |a Wang, Yilin  |e verfasserin  |4 aut 
700 1 |a Ye, Jianping  |e verfasserin  |4 aut 
700 1 |a Wang, Zhengping  |e verfasserin  |4 aut 
700 1 |a Yan, Haike  |e verfasserin  |4 aut 
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