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231223s2006 xx ||||| 00| ||eng c |
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|a eng
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|a Kwon, Ki-Young
|e verfasserin
|4 aut
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|a Oxadiazole-metal interface
|b from isolated molecules to pi-stacking
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|c 2006
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|2 rdacarrier
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|a Date Completed 01.05.2007
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|a Date Revised 24.01.2006
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a Derivatives of 2,5-diaryl-1,3,4-oxadiazole are used widely for electron transport in organic light emitting diodes (OLED). This study addresses the structure of 2,5-diphenyl-1,3,4-oxadiazole (PPD) molecules on Cu(111) using scanning tunneling microscopy (STM) and density function theory (DFT): at incomplete coverage, PPD molecules are found horizontally on the surface; once the surface area is insufficient to accommodate all adsorbates in this fashion, a pi-stacked film of vertically arranged molecules is formed. In contrast to bulk PPD, in this film, the molecules are arranged face-to-face at a separation of square root(3a0) = 4.4 A as imposed by the substrate interatomic spacing along the [-2 1 1] direction
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|a Journal Article
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|a Lin, Xing
|e verfasserin
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|a Pawin, Greg
|e verfasserin
|4 aut
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|a Wong, Kin
|e verfasserin
|4 aut
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|a Bartels, Ludwig
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 22(2006), 3 vom: 31. Jan., Seite 857-9
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|x 1520-5827
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|g year:2006
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|g day:31
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