Dynamic surface activity of phenylalanine glycerol-ether surfactant solutions measured by a differential maximum bubble pressure tensiometer

A refined differential maximum bubble pressure tensiometer was used for measuring the dynamic surface tension at various concentrations of a nonconventional surfactant, a member of a new homologous series of phenylalanine glycerol-ether amphiphiles, with 10 carbon atoms to the hydrophobic alkyl chai...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 22(2006), 1 vom: 03. Jan., Seite 46-51
1. Verfasser: Kalogianni, Eleni P (VerfasserIn)
Weitere Verfasser: Varka, Evi M, Karapantsios, Thodoris D, Pegiadou, Sofia
Format: Aufsatz
Sprache:English
Veröffentlicht: 2006
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Dynamic surface activity of phenylalanine glycerol-ether surfactant solutions measured by a differential maximum bubble pressure tensiometer 
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520 |a A refined differential maximum bubble pressure tensiometer was used for measuring the dynamic surface tension at various concentrations of a nonconventional surfactant, a member of a new homologous series of phenylalanine glycerol-ether amphiphiles, with 10 carbon atoms to the hydrophobic alkyl chain (C(10)-PhGE). The effective bubble formation frequency for the examined surfactant concentrations was varied from 2 bubbles per second to 1 bubble per 20 s. The variation of equilibrium surface tension with concentration as well as the critical micelle concentration were determined by a Wilhelmy plate technique. Comparisons between dynamic and equilibrium surface tension values demonstrate that, under the employed surface deformation rates, the equilibrium surface tension is a misleading indicator of surface activity. This is also supported by simple surface rheology considerations. Results based on a diffusion-controlled kinetic analysis provide further evidence on the strong dependence of surface activity on the particular time scale of deformation 
650 4 |a Journal Article 
700 1 |a Varka, Evi M  |e verfasserin  |4 aut 
700 1 |a Karapantsios, Thodoris D  |e verfasserin  |4 aut 
700 1 |a Pegiadou, Sofia  |e verfasserin  |4 aut 
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