Selenate removal from sulfate containing aqueous solutions

The performance of selenium remediation agents, mainly gamma alumina sorbents and zerovalent metals is greatly inhibited in the presence of large concentrations of sulfate found in selenium-rich agricultural drainage water. It is therefore imperative to remove sulfates from these contaminated waters...

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Veröffentlicht in:Environmental technology. - 1998. - 26(2005), 10 vom: 01. Okt., Seite 1181-7
1. Verfasser: Jegadeesan, G (VerfasserIn)
Weitere Verfasser: Mondal, K, Lalvani, S B
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Comparative Study Journal Article Research Support, Non-U.S. Gov't Barium Compounds Chlorides Metals Sulfates Water Pollutants, Chemical barium chloride 0VK51DA1T2 mehr... Carbon 7440-44-0 Selenium H6241UJ22B
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245 1 0 |a Selenate removal from sulfate containing aqueous solutions 
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500 |a Date Completed 21.07.2006 
500 |a Date Revised 21.11.2013 
500 |a published: Print 
500 |a Citation Status MEDLINE 
520 |a The performance of selenium remediation agents, mainly gamma alumina sorbents and zerovalent metals is greatly inhibited in the presence of large concentrations of sulfate found in selenium-rich agricultural drainage water. It is therefore imperative to remove sulfates from these contaminated waters, prior to their treatment for selenium removal. This paper presents data on enhanced selenium removal resulting from a two stage process involving the use of barium chloride in the first stage followed by a selenium remediation agent in the second. Barium chloride is known to stoichiometrically precipitate out sulfates. In addition to the sulfate removal from the contaminated solutions, a significant amount of selenate immobilization in the precipitated solids was achieved. When a loading of 15 g l(-1) of BaCl2, was employed, 100% selenate removal from an aqueous solution (containing 1 mg l(-1) selenate, 4 g l(-1) of sulfate and 2.5 g l(-1) of chloride) was achieved by the use of BaCl2, alone. Bimetallic NiFe particles, gamma alumina and activated carbon were employed to further remove selenium in the second stage. A solution containing 1 mg l(-1) and 4 g l(-1) of selenate and sulfate, respectively, when treated sequentially with 10 g l(-1) of BaCl2 and NiFe powder showed 100% selenium removal 
650 4 |a Comparative Study 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 7 |a Barium Compounds  |2 NLM 
650 7 |a Chlorides  |2 NLM 
650 7 |a Metals  |2 NLM 
650 7 |a Sulfates  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a barium chloride  |2 NLM 
650 7 |a 0VK51DA1T2  |2 NLM 
650 7 |a Carbon  |2 NLM 
650 7 |a 7440-44-0  |2 NLM 
650 7 |a Selenium  |2 NLM 
650 7 |a H6241UJ22B  |2 NLM 
700 1 |a Mondal, K  |e verfasserin  |4 aut 
700 1 |a Lalvani, S B  |e verfasserin  |4 aut 
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