17O NMR spectra of alpha-diesters

Copyright 2005 John Wiley & Sons, Ltd.

Bibliographische Detailangaben
Veröffentlicht in:Magnetic resonance in chemistry : MRC. - 1985. - 44(2006), 2 vom: 01. Feb., Seite 118-20
1. Verfasser: Cerioni, Giovanni (VerfasserIn)
Weitere Verfasser: Uccheddu, Gianluca
Format: Aufsatz
Sprache:English
Veröffentlicht: 2006
Zugriff auf das übergeordnete Werk:Magnetic resonance in chemistry : MRC
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Esters Oxygen Isotopes
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520 |a 17O NMR spectra of title compounds were measured at natural abundance in acetonitrile solutions. Intercarbonyl dihedral angles have been estimated by molecular mechanics, which show invariance except in one case. Because of this invariance, contrary to other alpha-dicarbonyl compounds, a correlation between chemical shifts and dihedral intercarbonyl angles could not be developed. Spectroscopic and computational results allowed us to evaluate other conformational features 
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