Facile preparation of nanoelectrode ensembles using amphiphilic block copolymer film

Taking advantage of both the self-organizing characteristics and the amphiphilic property of poly(styrene-block-ethyleneoxide) (P(S-b-EO)), we have realized one-step fabrication of nanoelectrode ensembles (NEEs). By choosing the electrolyte solution elaborately, only the poly(ethylene oxide) (PEO) s...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 21(2005), 25 vom: 06. Dez., Seite 11592-5
1. Verfasser: Hirota, Kouske (VerfasserIn)
Weitere Verfasser: Tajima, Keisuke, Hashimoto, Kazuhito
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
LEADER 01000naa a22002652 4500
001 NLM159200911
003 DE-627
005 20231223083653.0
007 cr uuu---uuuuu
008 231223s2005 xx |||||o 00| ||eng c
028 5 2 |a pubmed24n0531.xml 
035 |a (DE-627)NLM159200911 
035 |a (NLM)16316086 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Hirota, Kouske  |e verfasserin  |4 aut 
245 1 0 |a Facile preparation of nanoelectrode ensembles using amphiphilic block copolymer film 
264 1 |c 2005 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Completed 21.05.2015 
500 |a Date Revised 30.11.2005 
500 |a published: Print 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a Taking advantage of both the self-organizing characteristics and the amphiphilic property of poly(styrene-block-ethyleneoxide) (P(S-b-EO)), we have realized one-step fabrication of nanoelectrode ensembles (NEEs). By choosing the electrolyte solution elaborately, only the poly(ethylene oxide) (PEO) segment in the P(S-b-EO) film was swollen to serve as nanoscale tunnels for solvated ions, whereas the polystyrene segment remained robust to be the electrode mask. An electrochemical analysis indicated that a transition between linear diffusion and nonlinear diffusion could be observed due to the small diffusion coefficient of ferrocene in PEO nanodomains 
650 4 |a Journal Article 
700 1 |a Tajima, Keisuke  |e verfasserin  |4 aut 
700 1 |a Hashimoto, Kazuhito  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1992  |g 21(2005), 25 vom: 06. Dez., Seite 11592-5  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnns 
773 1 8 |g volume:21  |g year:2005  |g number:25  |g day:06  |g month:12  |g pages:11592-5 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 21  |j 2005  |e 25  |b 06  |c 12  |h 11592-5