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|a eng
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|a Hirota, Kouske
|e verfasserin
|4 aut
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|a Facile preparation of nanoelectrode ensembles using amphiphilic block copolymer film
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|c 2005
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 21.05.2015
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|a Date Revised 30.11.2005
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a Taking advantage of both the self-organizing characteristics and the amphiphilic property of poly(styrene-block-ethyleneoxide) (P(S-b-EO)), we have realized one-step fabrication of nanoelectrode ensembles (NEEs). By choosing the electrolyte solution elaborately, only the poly(ethylene oxide) (PEO) segment in the P(S-b-EO) film was swollen to serve as nanoscale tunnels for solvated ions, whereas the polystyrene segment remained robust to be the electrode mask. An electrochemical analysis indicated that a transition between linear diffusion and nonlinear diffusion could be observed due to the small diffusion coefficient of ferrocene in PEO nanodomains
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|a Journal Article
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|a Tajima, Keisuke
|e verfasserin
|4 aut
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|a Hashimoto, Kazuhito
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 21(2005), 25 vom: 06. Dez., Seite 11592-5
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|x 1520-5827
|7 nnns
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|g volume:21
|g year:2005
|g number:25
|g day:06
|g month:12
|g pages:11592-5
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|d 21
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|h 11592-5
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