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231223s2006 xx ||||| 00| ||eng c |
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|a pubmed24n0531.xml
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|a (DE-627)NLM159161827
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|a (NLM)16312017
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
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|a Milet, Anne
|e verfasserin
|4 aut
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|a Reaction of nitrones with silyl ketene acetals
|b a DFT study
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|c 2006
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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| 338 |
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|a Band
|b nc
|2 rdacarrier
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| 500 |
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|a Date Completed 19.04.2006
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|a Date Revised 15.11.2012
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|a published: Print
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|a Citation Status MEDLINE
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|a Copyright 2005 Wiley Periodicals, Inc.
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|a Theoretical calculations at the DFT level indicate that the reaction of a nitrone with a silyl ketene acetal proceeds, contrary to previous suggestions, through a classical 1,3-dipolar cycloaddition, followed by a silyl group transfer step to give the open-chain product. Introduction of a diffuse basis set is necessary to describe properly nitrones. The influence of a Lewis acid has been studied
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Acetals
|2 NLM
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| 650 |
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|a Ethylenes
|2 NLM
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| 650 |
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|a Ketones
|2 NLM
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| 650 |
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|a Nitrogen Oxides
|2 NLM
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| 650 |
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|a Organometallic Compounds
|2 NLM
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| 650 |
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|a Silanes
|2 NLM
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| 650 |
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|a nitrones
|2 NLM
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| 650 |
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|a ketene
|2 NLM
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| 650 |
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|a LEP3SM032A
|2 NLM
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| 700 |
1 |
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|a Gimbert, Yves
|e verfasserin
|4 aut
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1 |
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|a Greene, Andrew E
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Journal of computational chemistry
|d 1984
|g 27(2006), 2 vom: 30. Jan., Seite 157-62
|w (DE-627)NLM098138448
|x 1096-987X
|7 nnns
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| 773 |
1 |
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|g volume:27
|g year:2006
|g number:2
|g day:30
|g month:01
|g pages:157-62
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|a GBV_USEFLAG_A
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|a SYSFLAG_A
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|a GBV_NLM
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|a GBV_ILN_350
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|a AR
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|d 27
|j 2006
|e 2
|b 30
|c 01
|h 157-62
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