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|a DE-627
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|e rakwb
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|a eng
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|a Lee, Jungkyu K
|e verfasserin
|4 aut
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|a In-plane enyne metathesis and subsequent Diels-Alder reactions on self-assembled monolayers
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|c 2005
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
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|a Date Completed 04.05.2007
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|a Date Revised 02.11.2005
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a We report in-plane enyne metathesis and subsequent Diels-Alder reactions on self-assembled monolayers (SAMs) terminating in vinyl and acetylenyl groups on gold. After the formation of SAMs of vinyl and acetylenyl group-containing dithiols on gold, in-plane enyne metathesis of the vinyl and acetylenyl groups, leading to the formation of 1,3-diene, was achieved on the SAMs, and Diels-Alder reactions were then successfully performed with tetracyanoethylene, maleic anhydride, and maleimide. The reactions were confirmed by FT-IR spectroscopy, X-ray photoelectron spectroscopy, and time-of-flight secondary-ion mass spectrometry. In-plane enyne metathesis developed herein would offer a versatile platform for the functionalization of surfaces with mild reaction conditions and a high compatibility in functional groups
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|a Letter
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|a Chi, Young Shik
|e verfasserin
|4 aut
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|a Lee, Joon Sung
|e verfasserin
|4 aut
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|a Kim, Yang-Gyun
|e verfasserin
|4 aut
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|a Jung, Young Hwan
|e verfasserin
|4 aut
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|a Oh, Eugene
|e verfasserin
|4 aut
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|a Ko, Sung-Bo
|e verfasserin
|4 aut
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|a Jung, Hyuk-Jun
|e verfasserin
|4 aut
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|a Kang, Pill-Seong
|e verfasserin
|4 aut
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|a Choi, Insung S
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 21(2005), 23 vom: 08. Nov., Seite 10311-5
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|x 1520-5827
|7 nnns
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| 773 |
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|g year:2005
|g number:23
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|g month:11
|g pages:10311-5
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