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|a (DE-627)NLM158445856
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|a (NLM)16235219
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Eichel, Rüdiger-A
|e verfasserin
|4 aut
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|a High-field/high-frequency EPR of paramagnetic functional centers in Cu2+- and Fe3+-modified polycrystalline Pb[Zr(x)Ti(1-x)]O3 ferroelectrics
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|c 2005
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|a Band
|b nc
|2 rdacarrier
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|a Date Completed 22.12.2005
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|a Date Revised 24.10.2005
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a Copyright 2005 John Wiley & Sons, Ltd
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|a Copper(II)- and iron(III)-modified Pb[Zr(x)Ti(1-x)]O3 ferroelectrics were investigated by means of high-field/high-frequency EPR. The results obtained suggest that Cu2+ and Fe3+ both substitute as acceptor centers for [Zr,Ti]4+. Whereas for the iron-doped system the charge compensating oxygen vacancies (V(O)**) lead to the formation of charged (Fe'(Ti-)V(O)**)* defect associates, no such associates have been observed for the copper-modified system. As regards the morphotropic phase boundary, the model of a mesoscopic mixing of the pure-member phases has been refined to a picture in which a nanoscale composition distribution prevails
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|a Journal Article
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|a Mestrić, Hrvoje
|e verfasserin
|4 aut
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|a Dinse, Klaus-Peter
|e verfasserin
|4 aut
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|a Ozarowski, Andrew
|e verfasserin
|4 aut
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|a van Tol, Johan
|e verfasserin
|4 aut
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|a Brunel, Louis Claude
|e verfasserin
|4 aut
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|a Kungl, Hans
|e verfasserin
|4 aut
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|a Hoffmann, Michael J
|e verfasserin
|4 aut
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|i Enthalten in
|t Magnetic resonance in chemistry : MRC
|d 1985
|g 43 Spec no.(2005) vom: 15. Nov., Seite S166-73
|w (DE-627)NLM098179667
|x 1097-458X
|7 nnns
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|g volume:43 Spec no.
|g year:2005
|g day:15
|g month:11
|g pages:S166-73
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|a GBV_USEFLAG_A
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|a GBV_ILN_350
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|a AR
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|d 43 Spec no.
|j 2005
|b 15
|c 11
|h S166-73
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