|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM15844566X |
| 003 |
DE-627 |
| 005 |
20231223082210.0 |
| 007 |
tu |
| 008 |
231223s2005 xx ||||| 00| ||eng c |
| 028 |
5 |
2 |
|a pubmed24n0528.xml
|
| 035 |
|
|
|a (DE-627)NLM15844566X
|
| 035 |
|
|
|a (NLM)16235198
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Kay, Christopher W M
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Determination of the g-matrix orientation in flavin radicals by high-field/high-frequency electron-nuclear double resonance
|
| 264 |
|
1 |
|c 2005
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
|
| 338 |
|
|
|a Band
|b nc
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 22.12.2005
|
| 500 |
|
|
|a Date Revised 15.11.2006
|
| 500 |
|
|
|a published: Print
|
| 500 |
|
|
|a Citation Status MEDLINE
|
| 520 |
|
|
|a Copyright 2005 John Wiley & Sons, Ltd
|
| 520 |
|
|
|a A high-microwave-frequency/high-magnetic-field pulsed electron-nuclear double resonance (ENDOR) study performed at 94 GHz on the flavin semiquinone cofactor of Xenopus laevis (6-4) photolyase in its neutral radical state is presented. Although the principal values of the flavin radical's g-matrix are not fully resolved in the 94-GHz EPR spectrum in a nonoriented sample, the orientation of the principal axes of g is obtained by exploiting the orientation selection of the proton ENDOR signals from the methyl protons at C-8alpha and the deuteron ENDOR signals from D-5 in an enzyme sample in deuterated buffer. This procedure for assigning the orientation of g relative to the molecular frame makes use of commercially available ENDOR instrumentation without the necessity to perform single-crystal studies
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Research Support, Non-U.S. Gov't
|
| 650 |
|
7 |
|a Flavins
|2 NLM
|
| 650 |
|
7 |
|a Free Radicals
|2 NLM
|
| 700 |
1 |
|
|a Schleicher, Erik
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Hitomi, Kenichi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Todo, Takeshi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Bittl, Robert
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Weber, Stefan
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Magnetic resonance in chemistry : MRC
|d 1985
|g 43 Spec no.(2005) vom: 15. Nov., Seite S96-102
|w (DE-627)NLM098179667
|x 1097-458X
|7 nnns
|
| 773 |
1 |
8 |
|g volume:43 Spec no.
|g year:2005
|g day:15
|g month:11
|g pages:S96-102
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 43 Spec no.
|j 2005
|b 15
|c 11
|h S96-102
|