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|a pubmed24n0528.xml
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|a (DE-627)NLM158445597
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|a (NLM)16235191
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
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|a Knapp, Claus
|e verfasserin
|4 aut
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| 245 |
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|a Comparative EPR study of CuC60 and N@C60 endofullerenes
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|c 2005
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|a Band
|b nc
|2 rdacarrier
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|a Date Completed 22.12.2005
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|a Date Revised 24.10.2005
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a Copyright 2005 John Wiley & Sons, Ltd
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|a A comparative study of C60-based endohedral fullerenes was performed. From an analysis of spin relaxation times of the recently characterized CuC60 metallo-endofullerene, it could be shown that the encased ion occupies a well-defined off-centre position even at room temperature. Localization on the timescale of an EPR experiment is combined with charge transfer of approximately two electrons, resulting in the EPR signature of a 3d9 copper ion. This is in contrast to N@C60, for which a nearly complete decoupling from the cage is found. An upper limit for the variance of collision-induced modulation of the anisotropic nitrogen hfi is determined as (A(eff)2)(1/2) < 500 kHz by an analysis of cross peak intensities in a 2D EPR experiment. Pulsed 95 GHZ ENDOR experiments have been performed to confirm that deformation-induced hyperfine anisotropies are expected to be very small in N@C60
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|a Journal Article
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|a Weiden, Norbert
|e verfasserin
|4 aut
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|a Dinse, Klaus-Peter
|e verfasserin
|4 aut
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|i Enthalten in
|t Magnetic resonance in chemistry : MRC
|d 1985
|g 43 Spec no.(2005) vom: 15. Nov., Seite S199-204
|w (DE-627)NLM098179667
|x 1097-458X
|7 nnns
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| 773 |
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|g volume:43 Spec no.
|g year:2005
|g day:15
|g month:11
|g pages:S199-204
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|a GBV_ILN_350
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|a AR
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|d 43 Spec no.
|j 2005
|b 15
|c 11
|h S199-204
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