A model of polyelectrolyte conductance in moist solvents as a basis of water sensors

The conductance of interpenetrated polymer networks (IPNs) containing quaternary amino groups was studied in cyclohexane, toluene, ethyl ether, ethyl acetate, and tetrahydrofurane as a function of water content by electrochemical impedance spectroscopy. IPNs were then used as sensitive materials to...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 21(2005), 21 vom: 11. Okt., Seite 9704-8
1. Verfasser: Casalbore-Miceli, G (VerfasserIn)
Weitere Verfasser: Zanelli, A, Rinaldi, A W, Girotto, E M, Yang, M-J, Chen, Y-S, Li, Y
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 2 |a A model of polyelectrolyte conductance in moist solvents as a basis of water sensors 
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520 |a The conductance of interpenetrated polymer networks (IPNs) containing quaternary amino groups was studied in cyclohexane, toluene, ethyl ether, ethyl acetate, and tetrahydrofurane as a function of water content by electrochemical impedance spectroscopy. IPNs were then used as sensitive materials to detect water traces in organic solvents with promising results for the construction of a moisture sensor. The detection onset for water concentration increased with the dielectric constant of the solvent. Different IPN-based sensors in the same solvent showed a detection limit at lower water concentration if their characteristic plot [conductance/relative humidity (RH%) in air] was shifted toward lower RH%. This suggests that the composition of this class of polymers can be tuned to achieve the best performance for each solvent 
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700 1 |a Zanelli, A  |e verfasserin  |4 aut 
700 1 |a Rinaldi, A W  |e verfasserin  |4 aut 
700 1 |a Girotto, E M  |e verfasserin  |4 aut 
700 1 |a Yang, M-J  |e verfasserin  |4 aut 
700 1 |a Chen, Y-S  |e verfasserin  |4 aut 
700 1 |a Li, Y  |e verfasserin  |4 aut 
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