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|a pubmed24n0527.xml
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|a eng
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|a Casalbore-Miceli, G
|e verfasserin
|4 aut
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|a A model of polyelectrolyte conductance in moist solvents as a basis of water sensors
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|c 2005
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|a Band
|b nc
|2 rdacarrier
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|a Date Completed 10.04.2007
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|a Date Revised 06.10.2005
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a The conductance of interpenetrated polymer networks (IPNs) containing quaternary amino groups was studied in cyclohexane, toluene, ethyl ether, ethyl acetate, and tetrahydrofurane as a function of water content by electrochemical impedance spectroscopy. IPNs were then used as sensitive materials to detect water traces in organic solvents with promising results for the construction of a moisture sensor. The detection onset for water concentration increased with the dielectric constant of the solvent. Different IPN-based sensors in the same solvent showed a detection limit at lower water concentration if their characteristic plot [conductance/relative humidity (RH%) in air] was shifted toward lower RH%. This suggests that the composition of this class of polymers can be tuned to achieve the best performance for each solvent
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|a Journal Article
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|a Zanelli, A
|e verfasserin
|4 aut
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|a Rinaldi, A W
|e verfasserin
|4 aut
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|a Girotto, E M
|e verfasserin
|4 aut
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|a Yang, M-J
|e verfasserin
|4 aut
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|a Chen, Y-S
|e verfasserin
|4 aut
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|a Li, Y
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 21(2005), 21 vom: 11. Okt., Seite 9704-8
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|x 1520-5827
|7 nnns
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|g volume:21
|g year:2005
|g number:21
|g day:11
|g month:10
|g pages:9704-8
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|d 21
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|h 9704-8
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