Gold nanoparticle networks with photoresponsive interparticle spacings

Photoresponsive gold nanoparticle networks were prepared by functionalizing them with azobenzene derivatives. A network can be formed when a linker molecule constituting the azobenzene moiety suitably derivatized on either side with gold surface sensitive groups such as thiols and amines is added to...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 21(2005), 17 vom: 16. Aug., Seite 7979-84
1. Verfasser: Sidhaye, Deepti S (VerfasserIn)
Weitere Verfasser: Kashyap, Sudhir, Sastry, Murali, Hotha, Srinivas, Prasad, B L V
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Azo Compounds Gold 7440-57-5 azobenzene F0U1H6UG5C
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245 1 0 |a Gold nanoparticle networks with photoresponsive interparticle spacings 
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520 |a Photoresponsive gold nanoparticle networks were prepared by functionalizing them with azobenzene derivatives. A network can be formed when a linker molecule constituting the azobenzene moiety suitably derivatized on either side with gold surface sensitive groups such as thiols and amines is added to the nanoparticle solution. It is shown that the interparticle spacing in the networks could be controlled by the reversible trans-cis isomerization of the azobenzene moiety induced by UV and visible light, respectively. The photoinduced variation in the interparticle spacings is inferred by the changes in the optical spectra of the gold nanoparticles which display a red or blue shift in the surface plasmon resonance peak depending on a decrease or increase in the interparticle spacing, respectively. Transmission electron microscopy images are in consonance with the evidence from the optical spectra 
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650 4 |a Research Support, Non-U.S. Gov't 
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700 1 |a Kashyap, Sudhir  |e verfasserin  |4 aut 
700 1 |a Sastry, Murali  |e verfasserin  |4 aut 
700 1 |a Hotha, Srinivas  |e verfasserin  |4 aut 
700 1 |a Prasad, B L V  |e verfasserin  |4 aut 
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