4-Nitrobenzylamine partially intercalated into graphite powder and multiwalled carbon nanotubes : characterization using X-ray photoelectron spectroscopy and in situ atomic force microscopy

We report the characterization of partial intercalation of 4-nitrobenzylamine (4-NBA) into edge-plane or edge-plane-like defect sites on the surface of both graphite powder and "bamboo-like" multiwalled carbon nanotubes (MWCNTs) using X-ray photoelectron spectroscopy (XPS). By comparing th...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 21(2005), 10 vom: 10. Mai, Seite 4584-91
1. Verfasser: Wildgoose, Gregory G (VerfasserIn)
Weitere Verfasser: Hyde, Michael E, Lawrence, Nathan S, Leventis, Henry C, Jiang, Li, Jones, Timothy G J, Compton, Richard G
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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100 1 |a Wildgoose, Gregory G  |e verfasserin  |4 aut 
245 1 0 |a 4-Nitrobenzylamine partially intercalated into graphite powder and multiwalled carbon nanotubes  |b characterization using X-ray photoelectron spectroscopy and in situ atomic force microscopy 
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520 |a We report the characterization of partial intercalation of 4-nitrobenzylamine (4-NBA) into edge-plane or edge-plane-like defect sites on the surface of both graphite powder and "bamboo-like" multiwalled carbon nanotubes (MWCNTs) using X-ray photoelectron spectroscopy (XPS). By comparing the XPS spectra of 4-NBA derivatized graphite powder and MWCNTs with that of graphite powder treated with benzylamine in a similar fashion, we conclude that benzylamine itself does not undergo partial intercalation. Using in situ atomic force microscopy, we are able to observe the partial intercalation of 4-NBA into an edge-plane-like "step" defect on the surface of a highly ordered pyrolytic graphite crystal in real time. Together these observations provide further evidence for the partial intercalation of 4-NBA and lead us to propose a new hypothesis to explain this phenomenon 
650 4 |a Journal Article 
700 1 |a Hyde, Michael E  |e verfasserin  |4 aut 
700 1 |a Lawrence, Nathan S  |e verfasserin  |4 aut 
700 1 |a Leventis, Henry C  |e verfasserin  |4 aut 
700 1 |a Jiang, Li  |e verfasserin  |4 aut 
700 1 |a Jones, Timothy G J  |e verfasserin  |4 aut 
700 1 |a Compton, Richard G  |e verfasserin  |4 aut 
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