Odd-even effects in photoemission from terphenyl-substituted alkanethiolate self-assembled monolayers

Self-assembled monolayers (SAMs) formed from 4,4'-terphenyl-substituted alkanethiols C6H5(C6H4)2-(CH2)nSH (TPn, n = 1-6) on polycrystalline (111) gold and silver substrates have been characterized by synchrotron-based high-resolution X-ray photoelectron spectroscopy. The intensities, binding en...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 21(2005), 10 vom: 10. Mai, Seite 4370-5
1. Verfasser: Shaporenko, A (VerfasserIn)
Weitere Verfasser: Brunnbauer, M, Terfort, A, Johansson, L S O, Grunze, M, Zharnikov, M
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Odd-even effects in photoemission from terphenyl-substituted alkanethiolate self-assembled monolayers 
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520 |a Self-assembled monolayers (SAMs) formed from 4,4'-terphenyl-substituted alkanethiols C6H5(C6H4)2-(CH2)nSH (TPn, n = 1-6) on polycrystalline (111) gold and silver substrates have been characterized by synchrotron-based high-resolution X-ray photoelectron spectroscopy. The intensities, binding energy positions, and width of most photoemission lines exhibited pronounced odd-even effects, i.e., systematic and periodic variation, depending on either odd or even number of the methylene units in the aliphatic linker of the TPn molecules. The detailed analysis of these effects provides important information on the bonding and arrangement of the chemisorbed sulfur headgroups in the TPn films and balance of the structural forces in alkanethiolate SAMs 
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700 1 |a Terfort, A  |e verfasserin  |4 aut 
700 1 |a Johansson, L S O  |e verfasserin  |4 aut 
700 1 |a Grunze, M  |e verfasserin  |4 aut 
700 1 |a Zharnikov, M  |e verfasserin  |4 aut 
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