The role of the electrical double layer and ion pairing on the electrochemical oxidation of hexachloroiridate(III) at Pt electrodes of nanometer dimensions
The steady-state voltammetric oxidation of hexachloroiridate(III), IrCl6(3-) (1-5 mM), in the presence and absence of an excess supporting electrolyte was investigated at disk- and hemispherical-shaped Pt electrodes with radii ranging from 48 nm to 12.5 microm. Thermodynamic, kinetic, and transport...
| Publié dans: | Langmuir : the ACS journal of surfaces and colloids. - 1985. - 20(2004), 13 vom: 22. Juni, Seite 5474-83 |
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| Format: | Article |
| Langue: | English |
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2004
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| Accès à la collection: | Langmuir : the ACS journal of surfaces and colloids |
| Sujets: | Journal Article |