The role of the electrical double layer and ion pairing on the electrochemical oxidation of hexachloroiridate(III) at Pt electrodes of nanometer dimensions
The steady-state voltammetric oxidation of hexachloroiridate(III), IrCl6(3-) (1-5 mM), in the presence and absence of an excess supporting electrolyte was investigated at disk- and hemispherical-shaped Pt electrodes with radii ranging from 48 nm to 12.5 microm. Thermodynamic, kinetic, and transport...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 20(2004), 13 vom: 22. Juni, Seite 5474-83 |
|---|---|
| 1. Verfasser: | |
| Weitere Verfasser: | |
| Format: | Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2004
|
| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |