Fabrication of densely packed titania nanosheet films on solid surface by use of Langmuir-Blodgett deposition method without amphiphilic additives

Densely packed exfoliated nanosheet films such as Ti0.91O2, Ti0.8M0.2O2 (M = Co, Ni), Ti0.6Fe0.4O2, and Ca2Nb3O10 on solid substrates were prepared by the LB transfer method without any amphiphilic additives at the air-water interface. Nanosheet crystallites covered nearly 95% on the solid surface w...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 21(2005), 14 vom: 05. Juli, Seite 6590-5
1. Verfasser: Muramatsu, Masaru (VerfasserIn)
Weitere Verfasser: Akatsuka, Kosho, Ebina, Yasuo, Wang, Kezhi, Sasaki, Takayoshi, Ishida, Takao, Miyake, Koji, Haga, Masa-Aki
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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100 1 |a Muramatsu, Masaru  |e verfasserin  |4 aut 
245 1 0 |a Fabrication of densely packed titania nanosheet films on solid surface by use of Langmuir-Blodgett deposition method without amphiphilic additives 
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520 |a Densely packed exfoliated nanosheet films such as Ti0.91O2, Ti0.8M0.2O2 (M = Co, Ni), Ti0.6Fe0.4O2, and Ca2Nb3O10 on solid substrates were prepared by the LB transfer method without any amphiphilic additives at the air-water interface. Nanosheet crystallites covered nearly 95% on the solid surface with minimum overlapping of nanosheets. The LB transfer method of the Ti0.91O2 nanosheet monolayer film is applicable for not only hydrophilic substrates such as quartz, silicon, indium-tin oxide (ITO), and glass but also the hydrophobic Au surface. On the basis of these points, the LB transfer method has advantages compared to the alternating layer-by-layer method, which makes use of oppositely charged polyelectrolytes such as poly(ethylenimine) (PEI). Adsorption of hydrophobic Ti0.91O2 nanosheets at the air-water interface is responsible for this LB transfer deposition method. The addition of tetrabutylammonium bromide into the subphase assisted the adsorption, causing an increase in the adsorbed amount of Ti0.91O2 nanosheets at the air-water interface 
650 4 |a Journal Article 
700 1 |a Akatsuka, Kosho  |e verfasserin  |4 aut 
700 1 |a Ebina, Yasuo  |e verfasserin  |4 aut 
700 1 |a Wang, Kezhi  |e verfasserin  |4 aut 
700 1 |a Sasaki, Takayoshi  |e verfasserin  |4 aut 
700 1 |a Ishida, Takao  |e verfasserin  |4 aut 
700 1 |a Miyake, Koji  |e verfasserin  |4 aut 
700 1 |a Haga, Masa-Aki  |e verfasserin  |4 aut 
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