Reactivity of acetylenyl-terminated self-assembled monolayers on gold : triazole formation

We report the reactivity of acetylenyl-terminated self-assembled monolayers (SAMs) on gold toward "click" chemistry, Huisgen 1,3-dipolar addition, leading to the formation of triazoles. After the formation of acetylenyl-terminated SAMs, the triazole formation was performed on the SAMs and...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 20(2004), 10 vom: 11. Mai, Seite 3844-7
1. Verfasser: Lee, Jungkyu K (VerfasserIn)
Weitere Verfasser: Chi, Young Shik, Choi, Insung S
Format: Aufsatz
Sprache:English
Veröffentlicht: 2004
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Letter
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520 |a We report the reactivity of acetylenyl-terminated self-assembled monolayers (SAMs) on gold toward "click" chemistry, Huisgen 1,3-dipolar addition, leading to the formation of triazoles. After the formation of acetylenyl-terminated SAMs, the triazole formation was performed on the SAMs and the reaction was confirmed by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, ellipsometry, and contact angle goniometry. "Click" chemistry has offered a versatile strategy for the functionalization in solution chemistry with mild reaction conditions and a high compatibility in functional groups, and our result shows that the reaction could be applied to acetylenyl-terminated SAMs for the introduction of useful functional groups to the surfaces 
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700 1 |a Choi, Insung S  |e verfasserin  |4 aut 
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