Effect of the flow field on the rheological behavior of aqueous cetyltrimethylammonium p-toluenesulfonate solutions

It is well-known that solutions of cetyltrimethylammonium p-toluenesulfonate in water exhibit a pronounced shear-thickening phenomenon in a specific concentration range (0.1-0.8%) when they are subjected to simple-shear flows, as a consequence of flow-induced self-assembly of wormlike micelles. This...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1991. - 20(2004), 10 vom: 11. Mai, Seite 3838-41
1. Verfasser: Müller, A J (VerfasserIn)
Weitere Verfasser: Torres, M F, Sáez, A E
Format: Aufsatz
Sprache:English
Veröffentlicht: 2004
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Letter
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520 |a It is well-known that solutions of cetyltrimethylammonium p-toluenesulfonate in water exhibit a pronounced shear-thickening phenomenon in a specific concentration range (0.1-0.8%) when they are subjected to simple-shear flows, as a consequence of flow-induced self-assembly of wormlike micelles. This work shows that a strong elongational flow field (opposed-jets flow), applied to the same solutions, does not lead to extension thickening because the extensional flow prevents or destroys micellar association. In flow through a porous medium, a substantial increase in apparent viscosity is observed beyond a critical apparent shear rate, which surpasses increases observed in simple-shear flows. This is explained as the result of a synergistic effect of shear and relatively weak elongation on the solution microstructure 
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700 1 |a Sáez, A E  |e verfasserin  |4 aut 
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