Electrospun poly(styrene-block-dimethylsiloxane) block copolymer fibers exhibiting superhydrophobicity

Block copolymer poly(styrene-b-dimethylsiloxane) fibers with submicrometer diameters in the range 150-400 nm were produced by electrospinning from solution in tetrahydrofuran and dimethylformamide. Contact angle measurements indicate that the nonwoven fibrous mats are superhydrophobic, with a contac...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 21(2005), 12 vom: 07. Juni, Seite 5549-54
1. Verfasser: Ma, Minglin (VerfasserIn)
Weitere Verfasser: Hill, Randal M, Lowery, Joseph L, Fridrikh, Sergey V, Rutledge, Gregory C
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Electrospun poly(styrene-block-dimethylsiloxane) block copolymer fibers exhibiting superhydrophobicity 
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520 |a Block copolymer poly(styrene-b-dimethylsiloxane) fibers with submicrometer diameters in the range 150-400 nm were produced by electrospinning from solution in tetrahydrofuran and dimethylformamide. Contact angle measurements indicate that the nonwoven fibrous mats are superhydrophobic, with a contact angle of 163 degrees and contact angle hysteresis of 15 degrees . The superhydrophobicity is attributed to the combined effects of surface enrichment in siloxane as revealed by X-ray photoelectron spectroscopy and surface roughness of the electrospun mat itself. Additionally, the fibers are shown by transmission electron microscopy to exhibit microphase-separated internal structures. Calorimetric studies confirm the strong segregation between the polystyrene and poly(dimethylsiloxane) blocks 
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700 1 |a Hill, Randal M  |e verfasserin  |4 aut 
700 1 |a Lowery, Joseph L  |e verfasserin  |4 aut 
700 1 |a Fridrikh, Sergey V  |e verfasserin  |4 aut 
700 1 |a Rutledge, Gregory C  |e verfasserin  |4 aut 
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