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231223s2005 xx ||||| 00| ||eng c |
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|a pubmed24n0519.xml
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|a (DE-627)NLM155668447
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|a (NLM)15924444
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Cheng, Kai Wing
|e verfasserin
|4 aut
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|a Morphology of rhenium complex-containing polystyrene-block-poly(4-vinylpyridine) and its use as self-assembly templates for nanoparticles
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|c 2005
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|a Band
|b nc
|2 rdacarrier
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|a Date Completed 28.07.2006
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|a Date Revised 15.11.2006
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|a published: Print
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|a Citation Status MEDLINE
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|a Polystyrene-block-poly(4-vinylpyridine) was functionalized with a chlorotricarbonyl rhenium(I) diimine complex. Compared to the metal-free copolymer, the copolymer-metal complex exhibited different morphologies, which are highly sensitive to the solvent used for spin-coating and the surface properties of the substrates. Well-defined cylindrical or spherical domains were observed. Due to its ionic nature, the poly(4-vinylpyridine)--rhenium complex block could also serve as a template for subsequent deposition of cadmium sulfide nanoparticles by electrostatic attraction. The pattern of the deposited nanoparticles was found to be the replica of the block copolymer underneath, and their presence on the film surface was confirmed by X-ray photoelectron spectroscopy
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|a Letter
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|a Research Support, Non-U.S. Gov't
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|a Macromolecular Substances
|2 NLM
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|a Organometallic Compounds
|2 NLM
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|a Polystyrenes
|2 NLM
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|a Polyvinyls
|2 NLM
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|a Pyridines
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|a polystyrene-block-poly(4-vinylpyridine)
|2 NLM
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|a Rhenium
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|a 7440-15-5
|2 NLM
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|a Chan, Wai Kin
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 21(2005), 12 vom: 07. Juni, Seite 5247-50
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:21
|g year:2005
|g number:12
|g day:07
|g month:06
|g pages:5247-50
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