Self-assembled diisocyanide monolayer films on gold and palladium

Self-assembled monolayers (SAMs) of the aromatic diisocyanides, 1,4-phenylenediisocyanide, 2,3,5,6-tetramethyl-1,4-phenylenediisocyanide, 4,4'-biphenyldiisocyanide, 3,3',5,5'-tetramethyl-4,4'-biphenyldiisocyanide, and 4,4' '-p-terphenyldiisocyanide, were prepared on gol...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 21(2005), 11 vom: 24. Mai, Seite 5034-9
1. Verfasser: Swanson, Sally A (VerfasserIn)
Weitere Verfasser: McClain, Richard, Lovejoy, Katherine S, Alamdari, Neda B, Hamilton, Jeremy S, Scott, J Campbell
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
LEADER 01000naa a22002652 4500
001 NLM155397346
003 DE-627
005 20231223072039.0
007 tu
008 231223s2005 xx ||||| 00| ||eng c
028 5 2 |a pubmed24n0518.xml 
035 |a (DE-627)NLM155397346 
035 |a (NLM)15896047 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Swanson, Sally A  |e verfasserin  |4 aut 
245 1 0 |a Self-assembled diisocyanide monolayer films on gold and palladium 
264 1 |c 2005 
336 |a Text  |b txt  |2 rdacontent 
337 |a ohne Hilfsmittel zu benutzen  |b n  |2 rdamedia 
338 |a Band  |b nc  |2 rdacarrier 
500 |a Date Completed 14.06.2006 
500 |a Date Revised 17.05.2005 
500 |a published: Print 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a Self-assembled monolayers (SAMs) of the aromatic diisocyanides, 1,4-phenylenediisocyanide, 2,3,5,6-tetramethyl-1,4-phenylenediisocyanide, 4,4'-biphenyldiisocyanide, 3,3',5,5'-tetramethyl-4,4'-biphenyldiisocyanide, and 4,4' '-p-terphenyldiisocyanide, were prepared on gold and palladium surfaces. The SAMs were characterized by ellipsometry, polarization-modulated infrared reflection-absorption spectroscopy (PM-IRRAS), and grazing-angle attenuated total reflectance infrared spectroscopy (GATR). Based on the position of the metal-coordinated isocyanide stretching band, the SAMs on gold were found to bind in the terminal (eta(1)) geometry, while the SAMs on palladium prefer a different geometry which is possibly a triply bridging (mu(3)-eta(1)) geometry. A side-reaction of the unbound isocyanide in the SAM was identified as oxidation to an isocyanate group 
650 4 |a Journal Article 
700 1 |a McClain, Richard  |e verfasserin  |4 aut 
700 1 |a Lovejoy, Katherine S  |e verfasserin  |4 aut 
700 1 |a Alamdari, Neda B  |e verfasserin  |4 aut 
700 1 |a Hamilton, Jeremy S  |e verfasserin  |4 aut 
700 1 |a Scott, J Campbell  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1992  |g 21(2005), 11 vom: 24. Mai, Seite 5034-9  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnns 
773 1 8 |g volume:21  |g year:2005  |g number:11  |g day:24  |g month:05  |g pages:5034-9 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 21  |j 2005  |e 11  |b 24  |c 05  |h 5034-9