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|a pubmed24n0518.xml
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|a (DE-627)NLM155397346
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|a (NLM)15896047
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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1 |
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|a Swanson, Sally A
|e verfasserin
|4 aut
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|a Self-assembled diisocyanide monolayer films on gold and palladium
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|c 2005
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|a Band
|b nc
|2 rdacarrier
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|a Date Completed 14.06.2006
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|a Date Revised 17.05.2005
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a Self-assembled monolayers (SAMs) of the aromatic diisocyanides, 1,4-phenylenediisocyanide, 2,3,5,6-tetramethyl-1,4-phenylenediisocyanide, 4,4'-biphenyldiisocyanide, 3,3',5,5'-tetramethyl-4,4'-biphenyldiisocyanide, and 4,4' '-p-terphenyldiisocyanide, were prepared on gold and palladium surfaces. The SAMs were characterized by ellipsometry, polarization-modulated infrared reflection-absorption spectroscopy (PM-IRRAS), and grazing-angle attenuated total reflectance infrared spectroscopy (GATR). Based on the position of the metal-coordinated isocyanide stretching band, the SAMs on gold were found to bind in the terminal (eta(1)) geometry, while the SAMs on palladium prefer a different geometry which is possibly a triply bridging (mu(3)-eta(1)) geometry. A side-reaction of the unbound isocyanide in the SAM was identified as oxidation to an isocyanate group
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|a Journal Article
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|a McClain, Richard
|e verfasserin
|4 aut
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1 |
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|a Lovejoy, Katherine S
|e verfasserin
|4 aut
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1 |
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|a Alamdari, Neda B
|e verfasserin
|4 aut
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1 |
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|a Hamilton, Jeremy S
|e verfasserin
|4 aut
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|a Scott, J Campbell
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 21(2005), 11 vom: 24. Mai, Seite 5034-9
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:21
|g year:2005
|g number:11
|g day:24
|g month:05
|g pages:5034-9
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|a GBV_ILN_721
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|a AR
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|d 21
|j 2005
|e 11
|b 24
|c 05
|h 5034-9
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