|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM155397273 |
| 003 |
DE-627 |
| 005 |
20231223072039.0 |
| 007 |
tu |
| 008 |
231223s2005 xx ||||| 00| ||eng c |
| 028 |
5 |
2 |
|a pubmed24n0518.xml
|
| 035 |
|
|
|a (DE-627)NLM155397273
|
| 035 |
|
|
|a (NLM)15896040
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Lackinger, Markus
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Self-assembly of trimesic acid at the liquid-solid interface-a study of solvent-induced polymorphism
|
| 264 |
|
1 |
|c 2005
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
|
| 338 |
|
|
|a Band
|b nc
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 14.06.2006
|
| 500 |
|
|
|a Date Revised 17.05.2005
|
| 500 |
|
|
|a published: Print
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a A scanning tunneling microscope operated under ambient conditions was utilized to study the self-assembly of trimesic acid (TMA) at the liquid-solid interface. On a graphite substrate, two different open, loosely packed, two-dimensional hydrogen-bond networks were found. Both structures exhibit a periodic arrangement of approximately 1.0 nm wide cavities, which can be used for the co-adsorption of another species (guest) within the cells of this host system. These two polymorphs ("chickenwire" and "flower" structures) differ in their molecular packing density and hydrogen-bonding schemes. Using a homologous series of alkanoic acids as solvents, ranging from butyric to nonanoic, selective self-assembly of either the "flower" or "chickenwire" forms was achieved on a graphite surface. Solubility of TMA in these acid solvents was found to decrease with increasing chain length, and the longer-chain solvents favored formation of the chickenwire polymorph structure on the surface
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Griessl, Stefan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Heckl, Wolfgang M
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Hietschold, Michael
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Flynn, George W
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 21(2005), 11 vom: 24. Mai, Seite 4984-8
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:21
|g year:2005
|g number:11
|g day:24
|g month:05
|g pages:4984-8
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 21
|j 2005
|e 11
|b 24
|c 05
|h 4984-8
|