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|a DE-627
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|e rakwb
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|a eng
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|a Steytler, David C
|e verfasserin
|4 aut
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|a Retention of structure in microemulsion polymerization
|b formation of nanolatices
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|c 2004
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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|a Band
|b nc
|2 rdacarrier
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|a Date Completed 09.02.2006
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|a Date Revised 26.10.2019
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a Polymerization of styrene-in-water microemulsions by photoinitiation using the initiator 2,2'-dimethoxy-2-phenyl acetophenone (DMPA) produces small nanolatices of the same size as the parent microemulsion (radius = 24-31 angstroms). This behavior is distinct from previously applied methods where significant particle growth accompanies the polymerization reaction. NMR measurements confirmed that polymerization is complete in under an hour and small-angle neutron scattering established the microemulsion structure before and after polymerization. The approach may be of more general application where retention of structure is sought in microemulsion-based polymer templating procedures
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|a Journal Article
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|a Gurgel, Alexandre
|e verfasserin
|4 aut
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|a Ohly, Robert
|e verfasserin
|4 aut
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|a Jung, Martin
|e verfasserin
|4 aut
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|a Heenan, Richard K
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 20(2004), 9 vom: 27. Apr., Seite 3509-12
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|x 1520-5827
|7 nnns
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|g volume:20
|g year:2004
|g number:9
|g day:27
|g month:04
|g pages:3509-12
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|d 20
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|b 27
|c 04
|h 3509-12
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