Retention of structure in microemulsion polymerization : formation of nanolatices

Polymerization of styrene-in-water microemulsions by photoinitiation using the initiator 2,2'-dimethoxy-2-phenyl acetophenone (DMPA) produces small nanolatices of the same size as the parent microemulsion (radius = 24-31 angstroms). This behavior is distinct from previously applied methods wher...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 20(2004), 9 vom: 27. Apr., Seite 3509-12
1. Verfasser: Steytler, David C (VerfasserIn)
Weitere Verfasser: Gurgel, Alexandre, Ohly, Robert, Jung, Martin, Heenan, Richard K
Format: Aufsatz
Sprache:English
Veröffentlicht: 2004
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Polymerization of styrene-in-water microemulsions by photoinitiation using the initiator 2,2'-dimethoxy-2-phenyl acetophenone (DMPA) produces small nanolatices of the same size as the parent microemulsion (radius = 24-31 angstroms). This behavior is distinct from previously applied methods where significant particle growth accompanies the polymerization reaction. NMR measurements confirmed that polymerization is complete in under an hour and small-angle neutron scattering established the microemulsion structure before and after polymerization. The approach may be of more general application where retention of structure is sought in microemulsion-based polymer templating procedures 
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700 1 |a Heenan, Richard K  |e verfasserin  |4 aut 
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