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|a eng
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|a Bowers, James
|e verfasserin
|4 aut
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|a Aggregation behavior of aqueous solutions of ionic liquids
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|c 2004
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|a Text
|b txt
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|a ohne Hilfsmittel zu benutzen
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|a Date Completed 12.12.2005
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|a Date Revised 26.10.2019
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a The aggregation behavior in aqueous solutions of three ionic liquids based on the 1-alkyl-3-methylimidazolium cation has been investigated by means of surface tension, conductivity, and small-angle neutron scattering (SANS) measurements. From analysis of the SANS data, models for the shapes and sizes of aggregates have been proposed: the short-chain 1-butyl-3-methylimidazolium tetrafluoroborate [C4mim] [BF4] system can be best modeled by treating it as a dispersion of polydisperse spherical aggregates that form above a critical aggregation concentration, whereas the 1-octyl-3-methylimidazolium iodide, [C8mim] [I], solutions can be modeled as a system of regularly sized near-spherical charged micelles that form above a critical micelle concentration. Solutions of 1-octyl-3-methylimidazolium chloride, [C8mim]-[Cl], display weak long-range ordering of possibly disklike particles culminating in the formation of structures with distinct long-range order at higher concentrations
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|a Journal Article
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|a Butts, Craig P
|e verfasserin
|4 aut
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|a Martin, Pamela J
|e verfasserin
|4 aut
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|a Vergara-Gutierrez, Marcos C
|e verfasserin
|4 aut
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|a Heenan, Richard K
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 20(2004), 6 vom: 16. März, Seite 2191-8
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|x 1520-5827
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|g day:16
|g month:03
|g pages:2191-8
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