Aggregation behavior of aqueous solutions of ionic liquids

The aggregation behavior in aqueous solutions of three ionic liquids based on the 1-alkyl-3-methylimidazolium cation has been investigated by means of surface tension, conductivity, and small-angle neutron scattering (SANS) measurements. From analysis of the SANS data, models for the shapes and size...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 20(2004), 6 vom: 16. März, Seite 2191-8
1. Verfasser: Bowers, James (VerfasserIn)
Weitere Verfasser: Butts, Craig P, Martin, Pamela J, Vergara-Gutierrez, Marcos C, Heenan, Richard K
Format: Aufsatz
Sprache:English
Veröffentlicht: 2004
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a The aggregation behavior in aqueous solutions of three ionic liquids based on the 1-alkyl-3-methylimidazolium cation has been investigated by means of surface tension, conductivity, and small-angle neutron scattering (SANS) measurements. From analysis of the SANS data, models for the shapes and sizes of aggregates have been proposed: the short-chain 1-butyl-3-methylimidazolium tetrafluoroborate [C4mim] [BF4] system can be best modeled by treating it as a dispersion of polydisperse spherical aggregates that form above a critical aggregation concentration, whereas the 1-octyl-3-methylimidazolium iodide, [C8mim] [I], solutions can be modeled as a system of regularly sized near-spherical charged micelles that form above a critical micelle concentration. Solutions of 1-octyl-3-methylimidazolium chloride, [C8mim]-[Cl], display weak long-range ordering of possibly disklike particles culminating in the formation of structures with distinct long-range order at higher concentrations 
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700 1 |a Butts, Craig P  |e verfasserin  |4 aut 
700 1 |a Martin, Pamela J  |e verfasserin  |4 aut 
700 1 |a Vergara-Gutierrez, Marcos C  |e verfasserin  |4 aut 
700 1 |a Heenan, Richard K  |e verfasserin  |4 aut 
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