Chitosan-mediated and spatially selective electrodeposition of nanoscale particles

Nanoscale particles offer a variety of interesting properties, and there is growing interest in their assembly into higher ordered structures. We report that the pH-responsive aminopolysaccharide chitosan can mediate the electrodeposition of model nanoparticles. Chitosan is known to electrodeposit a...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 21(2005), 8 vom: 12. Apr., Seite 3641-6
1. Verfasser: Wu, Li-Qun (VerfasserIn)
Weitere Verfasser: Lee, Kyuyong, Wang, Xiang, English, Douglas S, Losert, Wolfgang, Payne, Gregory F
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Biocompatible Materials Fluorescent Dyes Latex Chitosan 9012-76-4
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520 |a Nanoscale particles offer a variety of interesting properties, and there is growing interest in their assembly into higher ordered structures. We report that the pH-responsive aminopolysaccharide chitosan can mediate the electrodeposition of model nanoparticles. Chitosan is known to electrodeposit at the cathode surface in response to a high localized pH. To demonstrate that chitosan can mediate nanoparticle deposition, we suspended fluorescently labeled latex nanoparticles (100 nm diameter spheres) in a chitosan solution (1%) and performed electrodeposition (0.05 mA/cm2 for several minutes). Results demonstrate that chitosan is required for nanoparticle electrodeposition; chitosan confers spatial selectivity to electrodeposition; and nanoparticles distribute throughout the electrodeposited chitosan film. Additionally, we observed that the deposited films reversibly swell upon rehydration. This work indicates that chitosan provides a simple means to assemble nanoparticles at addressable locations and provides further evidence that stimuli-responsive biological materials may facilitate fabrication at the microscale 
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650 4 |a Research Support, Non-U.S. Gov't 
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700 1 |a Lee, Kyuyong  |e verfasserin  |4 aut 
700 1 |a Wang, Xiang  |e verfasserin  |4 aut 
700 1 |a English, Douglas S  |e verfasserin  |4 aut 
700 1 |a Losert, Wolfgang  |e verfasserin  |4 aut 
700 1 |a Payne, Gregory F  |e verfasserin  |4 aut 
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