Robust self-assembled octadecylphosphonic acid monolayers on a mica substrate

As determined by scratch tests, self-assembled monolayers (SAMs) of octadecylphosphonic acid (OPA) on a muscovite mica substrate were found to be mechanically robust and to serve as a lubricant to protect the underlying mica substrate. For comparison purposes, three polymer films were subjected to s...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 21(2005), 7 vom: 29. März, Seite 2773-8
1. Verfasser: Nie, H-Y (VerfasserIn)
Weitere Verfasser: Miller, D J, Francis, J T, Walzak, M J, McIntyre, N S
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
LEADER 01000naa a22002652 4500
001 NLM154330884
003 DE-627
005 20231223065809.0
007 tu
008 231223s2005 xx ||||| 00| ||eng c
028 5 2 |a pubmed24n0515.xml 
035 |a (DE-627)NLM154330884 
035 |a (NLM)15779948 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Nie, H-Y  |e verfasserin  |4 aut 
245 1 0 |a Robust self-assembled octadecylphosphonic acid monolayers on a mica substrate 
264 1 |c 2005 
336 |a Text  |b txt  |2 rdacontent 
337 |a ohne Hilfsmittel zu benutzen  |b n  |2 rdamedia 
338 |a Band  |b nc  |2 rdacarrier 
500 |a Date Completed 14.06.2006 
500 |a Date Revised 22.03.2005 
500 |a published: Print 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a As determined by scratch tests, self-assembled monolayers (SAMs) of octadecylphosphonic acid (OPA) on a muscovite mica substrate were found to be mechanically robust and to serve as a lubricant to protect the underlying mica substrate. For comparison purposes, three polymer films were subjected to scratch tests under the same conditions. The scratch tests were conducted using a diamond-tipped stylus, and the resultant scratches were examined using atomic force microscopy. The excellent mechanical strength of OPA SAMs is supported by analysis with time-of-flight secondary ion mass spectrometry, which suggests that the headgroup of the OPA is strongly bonded to the substrate atoms. The molecular lubrication provided by OPA SAMs suggests that the interaction between the headgroup and the substrate is sufficiently strong to endure significant shear force and that the hydrocarbon chains are able to dissipate shear energy 
650 4 |a Journal Article 
700 1 |a Miller, D J  |e verfasserin  |4 aut 
700 1 |a Francis, J T  |e verfasserin  |4 aut 
700 1 |a Walzak, M J  |e verfasserin  |4 aut 
700 1 |a McIntyre, N S  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1992  |g 21(2005), 7 vom: 29. März, Seite 2773-8  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnns 
773 1 8 |g volume:21  |g year:2005  |g number:7  |g day:29  |g month:03  |g pages:2773-8 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 21  |j 2005  |e 7  |b 29  |c 03  |h 2773-8