Photooxidation of diglycine in confined media. Application of the microreactor model for spin-correlated radical pairs in reverse micelles and water-in-oil microemulsions
Time-resolved electron paramagnetic resonance spectra (X-band) of correlated radical pairs created in AOT reverse micelles and microemulsions are presented, simulated, and discussed using the microreactor model. The radicals are formed inside the water pool using photooxidation of diglycine by the e...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1985. - 21(2005), 7 vom: 29. März, Seite 2721-7 |
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| Weitere Verfasser: | , |
| Format: | Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2005
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S. Anthraquinones Emulsions Free Radicals Micelles Oils Water 059QF0KO0R mehr... |
| Zusammenfassung: | Time-resolved electron paramagnetic resonance spectra (X-band) of correlated radical pairs created in AOT reverse micelles and microemulsions are presented, simulated, and discussed using the microreactor model. The radicals are formed inside the water pool using photooxidation of diglycine by the excited triplet states of two different anthraquinone sulfonate salts. Water pool size and temperature effects on the spectra are reported, and the simulations allow for extraction of the diffusion coefficient in the interior, which monotonically increases with water pool size. The data directly correlate with the diffusional properties of correlated radical pairs in regular aqueous micelle solutions studied previously by similar methods. Competition between H-atom abstraction and electron transfer is observed with anthraquinone sulfonate, but electron transfer is the only reaction pathway observed when anthraquinone disulfonate triplet state is the sensitizing species |
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| Beschreibung: | Date Completed 14.06.2006 Date Revised 21.11.2013 published: Print Citation Status MEDLINE |
| ISSN: | 1520-5827 |