Tunneling characteristics of octadecyl derivatives on tin and indium electrodes

In this paper we report the tunneling behavior based on the capillary tunnel junctions of n-octadecylmercaptan (C18H37SH), octadecylamine (C18H37NH2), nonadecanoic acid (C17H35COOH), octadecanol (C18H370H), and n-iodooctadecane (C18H37I), sandwiched between tin and indium electrodes utilizing the na...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 20(2004), 3 vom: 03. Feb., Seite 855-61
1. Verfasser: Liu, Yuhong (VerfasserIn)
Weitere Verfasser: Fan, Xiaolin, Yang, Deliang, Wang, Chen, Wan, Lijun, Bai, Chunli
Format: Aufsatz
Sprache:English
Veröffentlicht: 2004
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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100 1 |a Liu, Yuhong  |e verfasserin  |4 aut 
245 1 0 |a Tunneling characteristics of octadecyl derivatives on tin and indium electrodes 
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520 |a In this paper we report the tunneling behavior based on the capillary tunnel junctions of n-octadecylmercaptan (C18H37SH), octadecylamine (C18H37NH2), nonadecanoic acid (C17H35COOH), octadecanol (C18H370H), and n-iodooctadecane (C18H37I), sandwiched between tin and indium electrodes utilizing the naturally existing oxide surfaces, respectively. The surfaces of the electrodes were examined by X-ray diffraction (XRD), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS) methods, and the self-assembled monolayers adsorbed on the electrode surfaces were inspected by contact angle measurements and XPS. The measured characteristic curves on tin electrode indicated a sequence of energy gaps associated with the specimen: deltaC17H35COOH > deltaC18H37OH > deltaC18H37SH > deltaC18H37NH2 > deltaC18lH37I. The results on the energy gaps obtained on indium electrodes displayed similar sequence behavior although with different gap values. The experimental observations indicate that the molecule-electrode contact, including both the functional groups and substrates, could contribute jointly to the overall conductance characteristics of molecular junctions 
650 4 |a Journal Article 
700 1 |a Fan, Xiaolin  |e verfasserin  |4 aut 
700 1 |a Yang, Deliang  |e verfasserin  |4 aut 
700 1 |a Wang, Chen  |e verfasserin  |4 aut 
700 1 |a Wan, Lijun  |e verfasserin  |4 aut 
700 1 |a Bai, Chunli  |e verfasserin  |4 aut 
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