Magnetic alignment of self-assembled anthracene organogel fibers

High magnetic fields are shown to be remarkably effective to orient self-assembled 2,3-bis-n-decyloxyanthracene (DDOA) fibers during organogel preparation. Magnetic orientation of DDOA results in a highly organized material displaying a fiber-orientation order parameter of 0.85, a large linear biref...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 21(2005), 6 vom: 15. März, Seite 2108-12
1. Verfasser: Shklyarevskiy, Igor O (VerfasserIn)
Weitere Verfasser: Jonkheijm, Pascal, Christianen, Peter C M, Schenning, Albertus P H J, Del Guerzo, André, Desvergne, Jean-Pierre, Meijer, E W, Maan, J C
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a High magnetic fields are shown to be remarkably effective to orient self-assembled 2,3-bis-n-decyloxyanthracene (DDOA) fibers during organogel preparation. Magnetic orientation of DDOA results in a highly organized material displaying a fiber-orientation order parameter of 0.85, a large linear birefringence, and fluorescence dichroism. The aligned organogel is stable after removal of the magnetic field at room temperature and consists of fibers oriented perpendicular to the magnetic field direction, as shown by scanning electron microscopy. Models for the molecular organization within the gel fibers are discussed upon quantitative analysis of the birefringence. Prospectively, magnetic alignment can be used to improve specific properties of organogel materials 
650 4 |a Journal Article 
700 1 |a Jonkheijm, Pascal  |e verfasserin  |4 aut 
700 1 |a Christianen, Peter C M  |e verfasserin  |4 aut 
700 1 |a Schenning, Albertus P H J  |e verfasserin  |4 aut 
700 1 |a Del Guerzo, André  |e verfasserin  |4 aut 
700 1 |a Desvergne, Jean-Pierre  |e verfasserin  |4 aut 
700 1 |a Meijer, E W  |e verfasserin  |4 aut 
700 1 |a Maan, J C  |e verfasserin  |4 aut 
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