Reduction of friction at oxide interfaces upon polymer adsorption from aqueous solutions

Reduction of the interfacial friction for the contact of a silicon oxide surface with sodium borosilicate in aqueous solutions has been accomplished through the adsorption of poly(L-lysine)-graft-poly(ethylene glycol) on one or both surfaces. Spontaneous polymer adsorption has been achieved via the...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 20(2004), 2 vom: 20. Jan., Seite 423-8
1. Verfasser: Yan, Xiaoping (VerfasserIn)
Weitere Verfasser: Perry, Scott S, Spencer, Nicholas D, Pasche, Stéphanie, De Paul, Susan M, Textor, Marcus, Lim, Min Soo
Format: Aufsatz
Sprache:English
Veröffentlicht: 2004
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Reduction of the interfacial friction for the contact of a silicon oxide surface with sodium borosilicate in aqueous solutions has been accomplished through the adsorption of poly(L-lysine)-graft-poly(ethylene glycol) on one or both surfaces. Spontaneous polymer adsorption has been achieved via the electrostatic attraction of the cationic polylysine polymer backbone and a net negative surface charge, present for a specific range of solution pH values. Interfacial friction has been measured in aqueous solution, in the absence of wear, and on a microscopic scale with atomic force microscopy. The successful investigation of the polymer-coated interfaces has been aided by the use of sodium borosilicate microspheres (5.1 microm diameter) as the contacting probe tip. Measurements of interfacial friction as a function of applied load reveal a significant reduction in friction upon the adsorption of the polymer, as well as sensitivity to the coated nature of the interface (single-sided versus two-sided) and the composition of the adsorbed polymer. These measurements demonstrate the fundamental opportunity for lubrication in aqueous environments through the selective adsorption of polymer coatings 
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700 1 |a Perry, Scott S  |e verfasserin  |4 aut 
700 1 |a Spencer, Nicholas D  |e verfasserin  |4 aut 
700 1 |a Pasche, Stéphanie  |e verfasserin  |4 aut 
700 1 |a De Paul, Susan M  |e verfasserin  |4 aut 
700 1 |a Textor, Marcus  |e verfasserin  |4 aut 
700 1 |a Lim, Min Soo  |e verfasserin  |4 aut 
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