Specimen charging in X-ray absorption spectroscopy : correction of total electron yield data from stabilized zirconia in the energy range 250-915 eV

The effects of specimen charging on X-ray absorption spectroscopy using total electron yield have been investigated using powder samples of zirconia stabilized by a range of oxides. The stabilized zirconia powder was mixed with graphite to minimize the charging but significant modifications of the i...

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Veröffentlicht in:Journal of synchrotron radiation. - 1994. - 12(2005), Pt 2 vom: 23. März, Seite 224-33
1. Verfasser: Vlachos, Dimitrios (VerfasserIn)
Weitere Verfasser: Craven, Alan J, McComb, David W
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Journal of synchrotron radiation
Schlagworte:Journal Article
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245 1 0 |a Specimen charging in X-ray absorption spectroscopy  |b correction of total electron yield data from stabilized zirconia in the energy range 250-915 eV 
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520 |a The effects of specimen charging on X-ray absorption spectroscopy using total electron yield have been investigated using powder samples of zirconia stabilized by a range of oxides. The stabilized zirconia powder was mixed with graphite to minimize the charging but significant modifications of the intensities of features in the X-ray absorption near-edge fine structure (XANES) still occurred. The time dependence of the charging was measured experimentally using a time scan, and an algorithm was developed to use this measured time dependence to correct the effects of the charging. The algorithm assumes that the system approaches the equilibrium state by an exponential decay. The corrected XANES show improved agreement with the electron energy-loss near-edge fine structure obtained from the same samples 
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700 1 |a McComb, David W  |e verfasserin  |4 aut 
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