Influence of the Al source and synthesis of ordered Al-SBA-15 hexagonal particles with nanostairs and terraces
We investigated the effect of various aluminum sources on the morphology and microstructure of nanoporous Al-SBA-15. With aluminum tri-sec-butoxide (Al-TSB), very large, ordered hexagonal rods of Al-SBA-15 covered by nanostairs and terraces were synthesized. Such a morphology was not obtained with a...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 21(2005), 5 vom: 01. März, Seite 2078-85 |
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| Weitere Verfasser: | , , |
| Format: | Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2005
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | We investigated the effect of various aluminum sources on the morphology and microstructure of nanoporous Al-SBA-15. With aluminum tri-sec-butoxide (Al-TSB), very large, ordered hexagonal rods of Al-SBA-15 covered by nanostairs and terraces were synthesized. Such a morphology was not obtained with an inorganic Al source (sodium aluminate) or with organic sources seemingly similar to Al-TSB, such as aluminum tri-tert-butoxide, aluminum tri-n-butoxide, or aluminum isopropoxide. The results obtained from X-ray diffraction, scanning electron microscopy/transmission electron microscopy, N(2) adsorption/desorption, and high-performance (129)Xe NMR suggest that preparing an organic Al-Si precursor by premixing liquid organic Al and Si sources (Al-TSB and tetraethyl orthosilicate) is crucial in obtaining highly ordered mesoporous Al-SBA-15 materials with a well-defined morphology |
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| Beschreibung: | Date Completed 13.06.2006 Date Revised 22.02.2005 published: Print Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |